Solid Flocculant Composition Suppressing Foam

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Solution Overview

Problem

Existing solid forms of flocculating auxiliaries used in solid-liquid separation processes tend to cause foaming, leading to process disruptions and the need for additional defoaming agents, which increase costs and complexity, while liquid forms have stability and transportation inefficiencies.

Innovation Solution

A composition combining non-ionic surfactants with ionic polymers in a specific weight ratio, eliminating the need for separate defoaming agents and maintaining performance by suppressing foaming effectively.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If solid forms of flocculating auxiliaries are used, then transportation costs are reduced and storage stability is improved, but foaming occurs during make-down or application processes

Engineering Contradiction:
Improvestorage stabilityVSAvoidfoaming
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent combines a flocculating auxiliary (ionic polymer) with a defoaming agent (non-ionic surfactant) into a single composite composition. The non-ionic surfactant is incorporated at concentrations of 0.01-5 wt.% within the flocculating auxiliary structure, allowing simultaneous flocculation and foam suppression functions in one product, thereby eliminating the harmful foaming effect while maintaining storage stability of the solid form.

Inventive Principle:
Principle #5Merging (Combining)

2Object-generated harmful factors

If additional defoaming agents are used, then foaming is suppressed, but device complexity and costs increase

Engineering Contradiction:
Improvefoaming suppressionVSAvoidadditional dosing equipment
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The defoaming agent (non-ionic surfactant) is integrated directly into the flocculating auxiliary composition during manufacturing, creating a unified product that performs both flocculation and foam suppression. This eliminates the need for separate defoaming agent storage tanks, dosing pumps, and injection systems, thereby reducing device complexity and operational costs while effectively suppressing foam.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The composite composition serves multiple functions simultaneously: the ionic polymer component provides flocculation activity for solid-liquid separation, while the incorporated non-ionic surfactant provides defoaming activity. This multi-functional design eliminates the need for separate single-function chemicals and their associated application equipment.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Object-generated harmful factors

If water-in-oil emulsions are used, then foaming is suppressed, but storage stability is reduced and larger volumes must be transported

Engineering Contradiction:
Improvefoaming suppressionVSAvoidstorage stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent changes the physical state parameter of the composition from liquid emulsion to solid form by controlling the water content to be at most 80 wt.%, preferably at most 60 wt.%, and more preferably at most 40 wt.%. This parameter change allows the composition to be stored and transported as a stable solid or semi-solid material while maintaining the foam-suppressing properties of the non-ionic surfactant, thereby improving storage stability and reducing transportation volumes compared to liquid water-in-oil emulsions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition efficiently suppresses foaming without impairing the performance of the flocculating auxiliaries, simplifying handling and metering, and offering improved storage stability and transportation efficiency compared to traditional forms.

Implementation Method 1

a non-ionic surfactant R 1[0020]wherein the content of the surfactant is within the range of from 0.05 to 2.0 wt.-%, preferably in the range of from 0.1 to 1.0 wt.-%, based on the total weight of the composition

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

The invention relates to compositions, preferably solid compositions, comprising a non-ionic surfactant and an ionic polymer... as flocculation auxiliaries for solid-liquid separation processes

Methodology Applied
Scientific EffectFlocculation: Flocculation

Data Source

PatentEP2768779B1Composition comprising a non-ionic surfactant and an ionic polymer
Publication Date: 2018.12.05 SOLENIS TECHNOLOGIES CAYMAN LP
  • EP2768779B1 patent drawingFigure 1
  • EP2768779B1 patent drawingFigure 2
  • EP2768779B1 patent drawing

AI summary

The invention relates to compositions, preferably solid compositions, comprising a non-ionic surfactant and an ionic polymer, methods for their preparation and their use. The compositions are useful inter alia as flocculation auxiliaries for solid-liquid separation processes, for example in sludge dewate ring/waste water purification and as retention aids or other additives in paper manufacture.