Solid Gel Dishwashing Detergent for Leak-Safe Pouches

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Solution Overview

Problem

Existing pre-portioned flowing gels used in washing and cleaning products, particularly machine dishwashing detergents, are prone to leakage and have aesthetically unappealing properties, which affects consumer perception and handling.

Innovation Solution

A gel-based dishwashing detergent formulation comprising specific ratios of polyvinyl alcohol, 1,3-propanediol, polyalkylene glycol, and glycerol, with optional additives like polyethylene glycol and zinc salts, that solidifies rapidly and remains dimensionally stable, preventing leakage and maintaining a visually appealing appearance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional gel formulations are used, then the gel provides cleaning function, but the gel leaks when packaged in single- or multi-chamber pouches

Engineering Contradiction:
Improveleak preventionVSAvoidpackaging difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the chemical composition parameters of the gel by incorporating specific polymers (carboxymethyl cellulose, hydroxyethyl cellulose), plasticizers (glycerol, sorbitol), and surfactants in controlled amounts to achieve optimal balance between flowability and structural integrity, preventing leakage while maintaining ease of manufacturing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite gel system combining multiple cellulose derivatives (carboxymethyl cellulose and hydroxyethyl cellulose) with plasticizers and surfactants to achieve synergistic effects that improve both leak prevention and manufacturability

Inventive Principle:
Principle #40Composite materials

2Productivity

If the gel solidifies slowly, then the gel maintains workability during production, but production time increases and costs increase

Engineering Contradiction:
Improveproduction speedVSAvoidsolidification time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent adjusts the molecular weight ranges and concentration ratios of cellulose derivatives and plasticizers to control the gel's solidification kinetics, enabling faster setting time (reducing production time) while maintaining adequate workability during the filling process

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the gel interacts with water-soluble coating, then the gel can be packaged, but discoloration and inactivation of ingredients occur

Engineering Contradiction:
Improveingredient stabilityVSAvoiddiscoloration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces a barrier layer or coating composition that acts as an intermediary between the gel and packaging materials, preventing direct interaction that causes discoloration and ingredient inactivation, while allowing the gel to maintain its cleaning functionality

Inventive Principle:
Principle #24Intermediary (Mediator)

4Ease of operation

If the gel has appealing feel and appearance, then consumer acceptance improves, but formulation complexity increases

Engineering Contradiction:
Improveconsumer acceptanceVSAvoidformulation complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent optimizes physical parameters including viscosity (through plasticizer selection), transparency (through purity control and particle size management), and tactile properties (through polymer concentration and crosslinking density) to achieve appealing consumer characteristics while managing formulation complexity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation ensures rapid solidification, minimal leakage, and maintains a translucent appearance, enhancing consumer acceptance and handling, while being cost-effective and easy to produce.

Implementation Method 1

which solidifies quickly and remains dimensionally stable

Methodology Applied
Scientific EffectSolidification: Phase Change

Data Source

PatentEP4067466B1Washing or cleaning agent
Publication Date: 2026.05.20 HENKEL KGAA
  • EP4067466B1 patent drawing
  • EP4067466B1 patent drawing

AI summary

The invention relates to washing or cleaning agents, preferably dishwashing detergents, in particular machine dishwashing detergents, comprising at least one gel, preferably a gel that is solid at room temperature (20°C), which, based on the total weight of the gel, contains: a) 10 to 20 wt.%, preferably 12 to 18 wt.%, in particular 12.7 to 15.5 wt.% PVOH and/or its derivatives, b) 27 to 35 wt.%, preferably 30.5 to 33 wt.%, in particular 31 to 32 wt.% 1,3-propanediol, c) 23 to 29.5 wt.%, preferably 25 to 28 wt.% glycerin, d) 12 to 18.5 wt.% polyalkylene glycol, in particular 13.5 to 16.5 wt.% polyalkylene glycol, and e) < 5 wt.%, preferably < 1 wt.% water.