Solid Hydrogen Storage via Metal Hydride Phase Transition

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Solution Overview

Problem

Current hydrogen storage methods, such as metal hydrides, face challenges with low energy storage density, high pressure requirements, and safety concerns due to the need for high-pressure operation, which complicates safe and efficient hydrogen storage for electricity generation.

Innovation Solution

An energy unit that incorporates a housing with a power source, electrolysis element, hydrogen storage element, and fuel cell, where hydrogen is produced from water through electrolysis and stored in solid form using a metal hydride, allowing for safe and stable storage and subsequent electricity generation, eliminating the need for high-pressure operation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen is stored using metal hydrides, then hydrogen can be stored in solid form, but energy storage density is low and storage tanks become considerably heavy

Engineering Contradiction:
Improvesafety of hydrogen storageVSAvoidweight of storage tank
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The patent changes the physical state parameter of hydrogen from gas to solid by using metal hydride storage. This transformation allows hydrogen to be stored in a stable solid form within the crystal lattice of metals or metal alloys, eliminating the need for high-pressure containment and significantly improving safety while reducing the weight and complexity of storage infrastructure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes the phase transition capability of metal hydrides, which can reversibly absorb and release hydrogen atoms. When hydrogen bonds to the metal to form metal hydride, it stores in a compact solid state. By applying heat or negative air pressure, the hydrogen can be released back to gas phase for fuel cell use, enabling safe and efficient cyclic storage and retrieval.

Inventive Principle:
Principle #36Phase transitions

2Quantity of substance

If hydrogen is stored at high pressure, then storage capacity increases, but safety concerns arise and system complexity increases

Engineering Contradiction:
Improvehydrogen storage capacityVSAvoidsafety risks
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent changes the storage pressure parameter from high pressure to low pressure by using metal hydride absorption. The metal hydride material naturally maintains hydrogen at relatively low pressures (450-800 psi) through its crystal lattice structure, eliminating the need for high-pressure containment systems and associated safety risks while maintaining adequate storage capacity.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If hydrogen is stored at high pressure, then storage capacity increases, but device complexity increases due to safety requirements

Engineering Contradiction:
Improvehydrogen storage capacityVSAvoidcomplexity of storage system
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent changes the storage pressure parameter from high to low, which fundamentally simplifies the storage system. Low-pressure operation eliminates the need for complex high-pressure containment vessels, pressure relief systems, and extensive safety monitoring infrastructure, while metal hydride materials provide inherent safety through their stable crystal lattice structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The metal hydride storage system provides self-regulating pressure control through the natural absorption and desorption characteristics of the metal hydride material. The system automatically maintains pressure within safe operating ranges (450-800 psi) based on the equilibrium between hydrogen absorption and release, eliminating the need for complex active pressure control systems.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The energy unit provides a portable, durable, and efficient means of producing and storing hydrogen in solid form, enabling safe and stable storage at low pressures, thereby addressing the limitations of existing hydrogen storage methods while facilitating electricity generation.

Implementation Method 1

an electrolysis element in the housing electrically connected to the power source and in fluid communication with the fluid chamber, the electrolysis chamber configured and operable to break the fluid down and to provide hydrogen gas

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

a hydrogen storage element in the housing connected to the electrolysis element and configured to store hydrogen in solid form

Methodology Applied
Scientific EffectMetal hydride storage: Absorption (physical)

Implementation Method 3

a fuel cell in the housing, connected to the hydrogen storage element and operable to generate electricity using at least hydrogen supplied from the hydrogen storage element

Methodology Applied
Scientific EffectFuel cell electrochemical reaction: Fuel Cell

Data Source

PatentEP2681792B1Energy unit with safe and stable hydrogen storage
Publication Date: 2020.11.18 KERNENE NICOLAS
  • EP2681792B1 patent drawingFigure 1
  • EP2681792B1 patent drawingFigure 2
  • EP2681792B1 patent drawingFigure 3

AI summary

An energy unit in accordance with an embodiment of the present application stores at least water and hydrogen. The energy unit includes an electrolysis component operable to provide hydrogen from the water, a hydrogen storage component operable to safely and stably store hydrogen in sold form and a fuel cell component operable to produce electricity from the hydrogen. The energy unit may be grouped with other like energy units to provide constant power for desired applications.