Solid Organosilane Powder for Cement-Free Mortar Hydrophobisation

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Solution Overview

Problem

Existing gypsum-based mortars without cement are sensitive to water, limiting their use in exterior applications and rooms with high moisture, and existing hydrophobizing solutions often require on-site mixing of powders with liquids, leading to quality issues and safety concerns.

Innovation Solution

A dry mortar formulation containing an organosilane and a water-soluble carrier material, where the organosilane has specific alkyl and alkoxy groups, and the carrier material is solid at room temperature, allowing for easy mixing with water to create a hydrophobic and storage-stable product with reduced water absorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If liquid silicon-based compounds are used as hydrophobising components, then water resistance is improved, but on-site mixing with liquids is required which leads to quality problems and safety concerns

Engineering Contradiction:
Improvewater resistanceVSAvoidhandling
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The invention changes the physical state of the hydrophobising agent from liquid to solid form. The organosilane is provided as a solid powder that can be directly incorporated into dry mortar formulations, eliminating the need for on-site liquid mixing while maintaining the hydrophobising effect. This parameter change resolves the contradiction by improving ease of operation without sacrificing water resistance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material by combining the solid organosilane with a carrier material. The carrier material serves as a support structure that allows the organosilane to be handled as a stable solid powder. This composite approach enables direct incorporation into dry mortars, eliminating liquid mixing requirements while preserving the hydrophobising functionality.

Inventive Principle:
Principle #40Composite materials

2Reliability

If powdery gypsum components are mixed with liquid silane-based compounds on site, then hydrophobicity is achieved, but additional expenses and quality problems arise

Engineering Contradiction:
ImprovehydrophobicityVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention merges the organosilane with a carrier material to create a unified solid powder formulation. This combined solid powder can be directly mixed with dry gypsum components in a single dry mixing process, eliminating the need for separate liquid addition and mixing steps. This reduces process complexity and manufacturing expenses while maintaining hydrophobicity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The organosilane is pre-combined with the carrier material to form a stable solid powder before use. This preliminary preparation eliminates the need for on-site liquid mixing operations, as the hydrophobising agent is already in the correct form for direct incorporation into dry mortar formulations, simplifying the manufacturing process.

Inventive Principle:
Principle #10Preliminary action

3Adaptability or versatility

If gypsum products are made hydrophobic, then exterior application capability is improved, but water sensitivity of gypsum materials must be overcome

Engineering Contradiction:
Improveapplication capabilityVSAvoidwater sensitivity
Core Design Contradiction:
Adaptability or versatilityVSObject-affected harmful factors

Solution Approach 1:

The solid organosilane acts as an intermediary substance that modifies the surface properties of gypsum materials. When incorporated into the mortar, it forms a hydrophobic barrier that mediates between the inherently water-sensitive gypsum and the external water environment, enabling exterior application capability while protecting against water sensitivity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the surface energy parameters of the gypsum material by incorporating the organosilane. This parameter change transforms the hydrophilic surface of gypsum into a hydrophobic surface, allowing the material to resist water penetration and enabling application in exterior and high-moisture environments.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides excellent hydrophobicity and reduced water absorption in gypsum-based and cement-free mortars, ensuring superior wettability and safety while eliminating the need for on-site liquid mixing, thus enhancing handling and logistics.

Implementation Method 1

contacting the mineral and/or filler in powder form with a hydrolysable organosilane, water, and a catalyst for hydrolysis and condensation of the organosilane under conditions such that the organosilane is hydrolysed in the presence of the mineral and/or filler

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

the organosilane hydrolysis product condenses to form polyorganosiloxane in the presence of the mineral or filler

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

GB 2 433 497 A describes a method of preparing a hydrophobic mineral and/or filler, which comprises contacting the mineral and/or filler in powder form with a hydrolysable organosilane

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Data Source

PatentEP2356084B2Powder to hydrophobise and its use
Publication Date: 2018.05.23 AKZO NOBEL CHEMICALS INTERNATIONAL BV

AI summary

The present invention relates to the use of a solid comprising at least one organosilane and a carrier material to hydrophobise mortars, wherein the organosilane has the formula R1Si(OR')3 or R1R2Si(OR')2 wherein R1 and R2 are the same or different and are a linear or branched C1- to C4- alkyl and/or alkenyl group, OR' is an acetoxy, a C1- to C4- alkoxy and/or a C2- to C6- methoxyalkoxy and/or ethoxyalkoxy group, and the carrier material is a solid at room temperature. The amount of cement in the final formulation is zero or less than 5 wt.-%, based on the total weight of the final formulation in the dry and uncured form. Claimed are also a powder comprising the silane and a carrier with the carrier being a water-soluble polymer, dry mortar formulations containing no or less than 5 wt.-% cement, based on the dry weight of the uncured mortar formulation, as well as processes to manufacture the formulations and/or compounds.