Solid Oxide Cell Modules With Heat Recovery for Methane Energy Storage

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Solution Overview

Problem

The challenge of efficiently storing excess electricity generated by non-fossil energy sources and using it to generate electricity when demand exceeds supply, while maintaining cost-effectiveness in the process.

Innovation Solution

A module comprising a solid oxide unit with multiple cells, heat exchangers, and a mixing and dosing unit, which recycles heat and gases to optimize energy use, and a subsystem with shared components to enhance power output and reduce costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If heat exchangers are added to recycle heat between process streams, then energy efficiency is improved, but device complexity increases

Engineering Contradiction:
Improveenergy efficiencyVSAvoiddevice complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The system recycles heat internally between process streams using heat exchangers, allowing the system to serve its own thermal needs without external energy input. Hot output air and gas mixtures from the solid oxide unit heat incoming air, water, and fuel streams, creating a self-sustaining thermal cycle that improves energy efficiency while integrating seamlessly into the existing system architecture.

Inventive Principle:
Principle #25Self-service

2Power

If multiple solid oxide cells are stacked together in a solid oxide unit, then power output is improved, but device complexity increases

Engineering Contradiction:
Improvepower outputVSAvoiddevice complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

Multiple solid oxide cells are stacked together in a single solid oxide unit, combining their individual power outputs into a unified system. This modular stacking approach achieves higher total power output while maintaining manageable complexity through standardized cell designs and integrated balance-of-plant components that serve the entire stack.

Inventive Principle:
Principle #5Merging (Combining)

3Manufacturing precision

If a mixing and dosing unit is added to combine steam and hydrogen in defined ratios, then manufacturing precision is improved, but device complexity increases

Engineering Contradiction:
Improvegas mixture precisionVSAvoiddevice complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The mixing and dosing unit precisely controls the composition of gas mixtures by adjusting flow rates and mixing ratios of steam and hydrogen. This parameter control ensures optimal conditions for methane production and solid oxide cell operation, achieving high manufacturing precision for gas composition while using straightforward mixing mechanisms that minimize added complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables efficient production and storage of methane for later electricity generation, reducing costs by recycling heat and sharing components, thus addressing the mismatch between energy supply and demand.

Implementation Method 1

A solid oxide cell is configured to produce hydrogen (H2) on the basis of a supply of electricity and gases including steam

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

to generate electricity on the basis of a supply of gases including methane in the electricity generation process

Methodology Applied
Scientific EffectFuel cell reaction: Fuel Cell

Implementation Method 3

a first heat exchanger arranged and configured to enable exchange of heat between output air of the solid oxide unit and water originating from a water supply

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentEP4586346A1Use of solid oxide cells in a methane production process and an electricity generation process
Publication Date: 2025.07.16 VAN PUTTEN ARNOLD JAN
  • EP4586346A1 patent drawingFigure 1~2
  • EP4586346A1 patent drawingFigure 3~4
  • EP4586346A1 patent drawingFigure 5~6

AI summary

In the field of using methane as an energy storage medium, wherein electricity is used at one stage for producing methane, and wherein methane is used at a later stage for generating electricity, use is made of solid oxide cells. The solid oxide cells are combined to stacks, the stacks are arranged in units (10), and the units (10) are arranged in modules (9). Each of the modules (9) is included in a subsystem (29) and is arranged in a frame (30) of the subsystem (29). Finally, a number of subsystems (29) are combined to a system. In this way, costs of the electricity to be generated are reduced. Further reduction of the costs is achieved by having components which are shared between the modules (9) and the subsystems (29), particularly components involved in supplying and discharging fluids and components involved in reusing heat of output fluid flows.