Solid Oxide Fuel Electrode Alloy Oxides Against Nickel Aggregation

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Solution Overview

Problem

The solid oxide cell faces durability issues due to nickel aggregation and expansion/contraction under high-temperature operating conditions, leading to structural destruction.

Innovation Solution

Incorporating alloy oxide particles of nickel (Ni) with a heterogeneous metal, such as tin (Sn), indium (In), bismuth (Bi), or gallium (Ga), into the fuel electrode, where the heterogeneous metal is more concentrated on the surface of the alloy oxide particles, delaying nickel contraction during firing and preventing aggregation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If nickel is used as the fuel electrode material to achieve high activity and low cost, then the catalyst performance is improved, but nickel aggregation and expansion/contraction occur under high-temperature operating conditions leading to structural destruction

Engineering Contradiction:
Improvecatalyst activityVSAvoidnickel structure stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies composite materials by combining nickel with heterogeneous metals (such as tin, indium, bismuth, or gallium) to form a nickel-based alloy. This composite structure maintains the high catalytic activity of nickel while the heterogeneous metal components prevent nickel aggregation and reduce thermal expansion/contraction, thereby resolving the contradiction between catalyst activity and structural stability under high-temperature operating conditions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by creating a non-uniform distribution of heterogeneous metals within the nickel structure. The heterogeneous metals are distributed at specific locations (such as grain boundaries or surface regions) to locally reinforce the structure and prevent aggregation, while maintaining nickel's catalytic properties in other regions. This localized modification resolves the contradiction by providing structural stability where needed without compromising overall catalyst activity.

Inventive Principle:
Principle #3Local quality

2Productivity

If nickel is evenly and widely spread within the solid oxide to increase three-phase boundary density, then fuel electrode performance is improved, but nickel aggregation under high-temperature conditions destroys the entire cell structure

Engineering Contradiction:
Improvefuel electrode performanceVSAvoidcell structure durability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent uses composite materials by forming a nickel-based alloy with heterogeneous metals that are evenly distributed throughout the solid oxide matrix. This composite approach allows nickel to be widely spread for high three-phase boundary density and performance, while the heterogeneous metal components act as structural stabilizers that prevent aggregation and maintain cell structure durability under high-temperature operating conditions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by modifying the chemical composition parameters of the fuel electrode material. By changing the composition from pure nickel to a nickel-based alloy with controlled amounts of heterogeneous metals (e.g., 0.1-10 at% Sn, In, Bi, or Ga), the material achieves both high dispersion for performance and aggregation resistance for durability, resolving the contradiction between productivity and reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases the density of the three-phase boundary, enhancing performance and preventing deterioration during fuel electrode operation, thereby improving the durability of the solid oxide cell.

Implementation Method 1

an alloy oxide particle of nickel (Ni) and a heterogeneous metal alloyable therewith

Methodology Applied
Scientific EffectAlloying:

Implementation Method 2

delaying a contraction of nickel (Ni) during firing of the fuel electrode

Methodology Applied
Scientific EffectThermal contraction delay:

Implementation Method 3

a solid oxide electrolyte having oxygen ionic conductivity

Methodology Applied
Scientific EffectOxygen ionic conductivity:

Implementation Method 4

generate electrical energy through an electrochemical reaction of a cell composed of an air electrode, a fuel electrode

Methodology Applied
Scientific EffectElectrochemical reaction:

Implementation Method 5

an electrochemical reaction

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 6

a reverse reaction of the solid oxide fuel cell

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS20250140876A1Solid oxide cell and manufacturing method thereof
Publication Date: 2025.05.01 SAMSUNG ELECTRO MECHANICS CO LTD
  • US20250140876A1 patent drawing
  • US20250140876A1 patent drawing
  • US20250140876A1 patent drawing

AI summary

A solid oxide cell includes a solid oxide electrolyte, and a fuel electrode disposed on one side of the solid oxide electrolyte and an air electrode disposed on the other side thereof. The fuel electrode includes alloy oxide particles of nickel (Ni) and a heterogeneous metal alloyable therewith and a solid oxide electrolyte material, and when an atomic percentage (at %) of the heterogeneous metal to all atoms in a center region of the alloy oxide particle is Mcore and an atomic percentage (at %) of the heterogeneous metal to all atoms in a surface region of the alloy particle is Msurface 10×Mcore<Msurface.