Solid Pigment Preparations with Aldehyde Resin

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Solution Overview

Problem

Existing pigment preparations fail to achieve homogeneous mixing of organic and inorganic pigments, leading to suboptimal incorporation into application media and color strength, particularly in the red-orange-yellow color range, where lead chromate and lead molybdate pigments are being phased out.

Innovation Solution

A process involving comminution of organic and inorganic pigments in an aqueous medium with a water-soluble/water-dilutable aldehyde or ketone resin, ensuring uniform wetting and mixing, resulting in pigment preparations with high color strength and homogeneity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If organic and inorganic pigments are mixed by dry grinding, then the process is simple and quick, but the mixing homogeneity is poor and incorporation into application media is suboptimal

Engineering Contradiction:
Improvemixing homogeneityVSAvoidprocess complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

A water-soluble/water-dilutable aldehyde or ketone resin is introduced as an intermediary substance to facilitate homogeneous mixing of organic and inorganic pigments. The resin acts as a binding medium that promotes uniform distribution of pigment particles and improves incorporation into application media, resolving the contradiction between mixing quality and process simplicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the physical state and composition parameters by introducing a resin component (0.5 to 20% by weight) into the pigment mixture. This parameter change transforms the dry mixing process into a resin-bound pigment preparation process, achieving superior mixing homogeneity while maintaining practical applicability.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If dispersants are added during aqueous grinding, then pigment dispersion improves, but the number of additives and process complexity increase

Engineering Contradiction:
Improvepigment dispersionVSAvoidnumber of additives
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The aldehyde or ketone resin performs multiple functions simultaneously: it acts as a binding agent, a dispersant, and a medium for homogeneous pigment mixing. This multi-functionality eliminates the need for separate dispersant additives, achieving good pigment dispersion while minimizing the number of substances added to the system.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of operation

If resin is used to bind pigments, then incorporation into application media improves, but color strength may be diluted

Engineering Contradiction:
Improveincorporation into application mediaVSAvoidcolor strength
Core Design Contradiction:
Ease of operationVSIllumination intensity

Solution Approach 1:

The invention optimizes the resin content parameter (0.5 to 20% by weight) to achieve the right balance between incorporation ease and color strength. By controlling the resin-to-pigment ratio, the preparation maintains high color strength while benefiting from improved incorporation properties provided by the resin binder.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves a homogeneous mixing of organic and inorganic pigments, maintaining or exceeding the color strength of dry-mixed preparations, and is suitable for various applications including paints, inks, plastics, and cosmetics, with the resin's modification allowing for improved pigment dispersion and stability.

Implementation Method 1

ensuring uniform wetting and mixing

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentEP1973975B1Solid pigment preparations containing resin
Publication Date: 2011.07.13 BASF SE

AI summary

The invention relates to solid pigment preparations containing, as essential components, (A) 80 to 99.5 wt. % of a pigment component from at least one organic pigment (A1) and an inorganic pigment (A2) and (B) 0.5 to 20 wt.- % of at least one water-soluble/water-dilutable aldehyde or ketone resin.