Solid Polymer Composition for Luminescent Crystals

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Solution Overview

Problem

Luminescent crystals, particularly quantum dots, integrated into polymer composites for light-emitting devices face issues with thermal instability, limiting their application in display technologies due to degradation when excited by background lighting.

Innovation Solution

A solid polymer composition comprising luminescent crystals, surfactants, and a hardened/cured polymer, where the luminescent crystals are selected from specific compounds of formula (I) and embedded in a polymer matrix to enhance thermal stability and optical properties, allowing for controlled emission of light in response to excitation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If luminescent crystals are integrated into polymer composites for light-emitting devices, then optical properties and light emission efficiency are improved, but thermal stability deteriorates causing degradation when excited by background lighting

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidthermal stability
Core Design Contradiction:
Use of energy by moving objectVSStability of the object's composition

Solution Approach 1:

The patent uses a composite material system consisting of luminescent crystals (quantum dots) embedded in a polymer matrix. This composite structure allows the luminescent crystals to provide high light emission efficiency while the polymer matrix provides thermal stability and structural support, resolving the contradiction between optical performance and thermal stability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the polymer matrix composition and crosslinking density to enhance thermal stability. By changing the chemical parameters of the polymer system (using specific monomers, crosslinkers, and ratios), the material maintains its structural integrity at elevated temperatures while preserving the luminescent properties of the embedded crystals

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If luminescent crystals are used in light emitting devices, then brightness and optical performance are improved, but reliability deteriorates due to degradation under excitation

Engineering Contradiction:
ImprovebrightnessVSAvoiddevice reliability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The polymer matrix acts as an intermediary between the luminescent crystals and the external environment. It protects the crystals from degradation caused by oxygen, moisture, and mechanical stress while allowing optical excitation and emission to occur efficiently, thereby maintaining both brightness and reliability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs a polymer encapsulation strategy that creates a protective barrier around the luminescent crystals. This encapsulation layer is designed to be stable under operating conditions, preventing crystal degradation and extending device lifetime without interfering with optical performance

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a thermally stable and efficient light-emitting component with improved photoluminescence quantum yield and sharp wavelength distributions, enabling effective use in display technologies while maintaining RoHS compliance.

Implementation Method 1

The luminescent crystals of the first solid polymer composition emit light of a first wavelength in response to excitation by light with a wavelength shorter than the first wavelength

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS11098247B2Solid polymer composition
Publication Date: 2021.08.24 AVANTAMA AG
  • US11098247B2 patent drawing
  • US11098247B2 patent drawing
  • US11098247B2 patent drawing

AI summary

The present invention relates in a first aspect to a solid polymer component comprising luminescent crystals of 3-500 nm size, surfactant and a hardened/cured polymer. In a second aspect of the invention, a luminescent component comprises a first element comprising the solid polymer component according to the first aspect and an encapsulation enclosing the first element. In a third aspect of the invention, a luminescent component comprises a first film comprising the solid polymer composition of the first aspect. A fourth aspect of the invention relates to a light emitting device comprising the luminescent component according to the second or third aspect of the invention and a light source.