Solid Rinse Aid for High TDS Water Without Metal Corrosion

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Solution Overview

Problem

Current rinse aid compositions are not environmentally friendly, can corrode metal surfaces, and are ineffective in high total dissolved solids and hard water conditions, while also being high-foaming, which interferes with warewashing machines.

Innovation Solution

A solid rinse aid composition combining a solid acid with short-chain alkylbenzene and alkyl naphthalene sulfonates, such as sodium xylene sulfonate, and a nonionic low foaming surfactant, designed for pressed or extruded solid formation, to create a rinse aid that is biodegradable, non-corrosive, and effective in hard water and high total dissolved solids conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional rinse aids are used, then spotless surfaces can be achieved, but metal surfaces are corroded and environmental friendliness is compromised

Engineering Contradiction:
Improvesurface qualityVSAvoidmetal corrosion
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the rinse aid by using specific surfactant combinations (anionic surfactants with nonionic surfactants) and controlling pH levels (pH 6.5-8.5) to achieve spotless surfaces while eliminating metal corrosion. This parameter optimization allows the rinse aid to function effectively without harmful side effects

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite surfactant systems combining multiple types of surfactants (anionic surfactants such as alkylbenzene sulfonates with nonionic surfactants) to create a synergistic effect that provides both spotless surface results and metal protection, while also incorporating biodegradable components for environmental friendliness

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If high foaming surfactants are used, then spotless surfaces can be achieved, but warewashing machine operation is interfered with

Engineering Contradiction:
Improvesurface qualityVSAvoidmachine operation
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The patent optimizes the foaming characteristics by selecting specific surfactant types and concentrations that produce low foam levels. The use of nonionic surfactants in combination with anionic surfactants, along with controlling the cloud point and HLB values, enables the rinse aid to provide spotless surfaces while maintaining low foam that does not interfere with automatic warewashing machine operation

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If conventional rinse aids are used, then spotless surfaces can be achieved, but effectiveness in hard water and high TDS conditions is poor

Engineering Contradiction:
Improvesurface qualityVSAvoidwater condition adaptability
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The invention uses composite surfactant systems that combine anionic surfactants (such as alkylbenzene sulfonates, alpha-olefin sulfonates) with nonionic surfactants. This combination creates a synergistic effect that enhances performance in various water conditions, including hard water and high TDS environments, while still achieving spotless surfaces

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes surfactant selection based on their HLB (hydrophile-lipophile balance) values and cloud points to ensure effective performance across different water conditions. The surfactant combination is designed to maintain effectiveness regardless of water hardness or TDS levels, providing consistent spotless results

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If biodegradable and environmentally friendly rinse aids are used, then environmental impact is reduced, but performance in high TDS and hard water conditions deteriorates

Engineering Contradiction:
Improveenvironmental impactVSAvoidwater condition adaptability
Core Design Contradiction:
Object-affected harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent employs biodegradable anionic surfactants (such as alkylbenzene sulfonates, alpha-olefin sulfonates) combined with nonionic surfactants to create an environmentally friendly rinse aid that maintains high performance. The composite surfactant system ensures effective operation in hard water and high TDS conditions while being biodegradable and environmentally safe

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides spotless surfaces without corrosion, effectively handles high total dissolved solids and hard water, and reduces foaming, making it suitable for metal surfaces and warewashing applications.

Implementation Method 1

One theory holds that the surfactant in the rinse agent is absorbed on the surface at temperatures at or above its cloud point, and thereby reduces the solid-liquid interfacial energy and contact angle

Methodology Applied
Scientific EffectSurfactant absorption: Adsorption

Implementation Method 2

the surfactant in the rinse agent is absorbed on the surface at temperatures at or above its cloud point

Methodology Applied
Scientific EffectCloud point: Phase Change

Data Source

PatentUS20240101931A1Solid fast draining/drying rinse aid for high total dissolved solid water conditions
Publication Date: 2024.03.28 ECOLAB USA INC
  • US20240101931A1 patent drawing
  • US20240101931A1 patent drawing
  • US20240101931A1 patent drawing

AI summary

The invention includes a solid rinse aid that is particularly designed for pressed or extrusion solid formation and which is effective for spotless surfaces after rinsing, especially rinsing metals without corrosion. According to the invention, a solid acid is combined with a short-chain alkylbenzene and alkyl naphthalene sulfonate. The short-chain alkylbenzene and alkyl naphthalene sulfonate act as a solidification agent as well as a hydrotrope, and total dissolved solid (TDS) active and are combined with at least one nonionic low foaming surfactant.