Solid Rinse Aid Composition for High TDS Water

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Solution Overview

Problem

Current rinse aid compositions for warewashing machines are not environmentally friendly and often contain phosphates and aminocarboxylates, and they do not effectively prevent spotting and filming on various surfaces, especially in high solids containing water environments.

Innovation Solution

A solid rinse aid composition incorporating short-chain alkyl benzene and alkyl naphthalene sulfonates as a solidification agent, combined with a surfactant system including alcohol ethoxylates, defoaming agents, and association disruption agents, which are biodegradable and GRAS-approved, to reduce spotting and filming by enhancing wetting and drying properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional rinse aid compositions containing phosphates and aminocarboxylates are used, then drying performance is improved, but environmental friendliness deteriorates

Engineering Contradiction:
Improvedrying performanceVSAvoidenvironmental friendliness
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters by replacing phosphates and aminocarboxylates with biodegradable surfactants having specific HLB values (10-16), molecular weights (500-5000), and cloud points (100-180°F). This parameter transformation maintains effective drying performance while eliminating environmentally harmful substances, achieving both reliability and environmental compatibility.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If high foaming surfactants are used to promote sheet formation, then wetting performance is improved, but interference with warewashing machine operation occurs

Engineering Contradiction:
Improvewetting performanceVSAvoidfoaming interference
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The invention applies local quality by selecting surfactants with specific localized properties: HLB values between 10-16 for optimal wetting, cloud points between 100-180°F for sheet formation at rinse temperatures, and controlled foaming characteristics. This targeted specification of local molecular properties achieves effective wetting and sheeting while minimizing harmful foaming that interferes with machine operation.

Inventive Principle:
Principle #3Local quality

3Object-affected harmful factors

If rinse aids are used in high total dissolved solid water conditions, then spotting prevention is needed, but conventional compositions fail to prevent filming

Engineering Contradiction:
Improvespotting preventionVSAvoidfilming prevention
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention uses composite materials by combining multiple surfactant components with complementary properties: primary surfactants for wetting, secondary surfactants for sheet formation, and biodegradable additives for water solids management. This composite surfactant system synergistically prevents both spotting and filming in high TDS conditions, achieving reliable performance where single-component conventional rinses fail.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively reduces spotting and filming on diverse surfaces, including plastics, glass, and metals, while being environmentally friendly and suitable for use in high solids containing water, improving drying times and sheeting action without foaming issues.

Implementation Method 1

the surfactant in the rinse agent is absorbed on the surface at temperatures at or above its cloud point

Methodology Applied
Scientific EffectCloud point:

Implementation Method 2

reduces the solid-liquid interfacial energy and contact angle

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Implementation Method 3

This leads to the formation of a continuous sheet which drains evenly from the surface

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 4

the short-chain alkylbenzene and alkyl naphthalene sulfonates class of hydrotopes which are traditionally included at low concentrations in detergents and rinse aids, when included at higher percentages, can act as a solidification aid

Methodology Applied
Scientific EffectSolidification: Freezing

Implementation Method 5

improving drying times and sheeting action

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 6

enhancing wetting and drying properties

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentUS20240052267A1Solid fast draining/drying rinse aid for high total dissolved solid water conditions
Publication Date: 2024.02.15 ECOLAB USA INC
  • US20240052267A1 patent drawing
  • US20240052267A1 patent drawing
  • US20240052267A1 patent drawing

AI summary

The present invention is a solid rinse aid composition and methods of making and using the same. Applicants have surprisingly found that the crystal modifier sodium xylene sulfonate (short chain alkyl benzene or alkyl naphthalene sulfonates) at higher percentage can act as a solidification agent. The solid rinse aid composition generally includes a short chain alkyl benzene or alkyl naphthalene sulfonates solidification agent and an effective amount of a surfactant which can include a sheeting agent component, defoamer component and/or association disruption agent. The solid rinse aid composition may be phosphate-free, aminocarboxylate-free, and GRAS if desired.