Solid Soil Release Polymer Composition for Polyester Stain Removal

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Solution Overview

Problem

Current laundry processes face challenges in removing residual alkalinity and oily stains from synthetic fabrics, particularly polyester, due to the instability of soil release polymers in alkaline and acidic environments, and the need for environmentally friendly and sustainable solutions.

Innovation Solution

A physically and chemically stable solid composition combining a soil release polymer and an acidulant is developed, which can be used in a post-wash step to neutralize alkalinity and remove oily stains, formulated to remain stable during aqueous dispensing and formed through processes like melting, casting, or pressing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If soil release polymer is used in liquid sour treatment, then oily stain removal is improved, but chemical stability deteriorates due to reaction with acid or oxidizer

Engineering Contradiction:
Improveoily stain removal effectivenessVSAvoidpolymer stability in acid environment
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent extracts the soil release polymer from the liquid sour treatment environment and places it in a solid detergent composition instead. This separation allows the polymer to remain stable during storage while still providing oily stain removal functionality when the detergent is used, resolving the contradiction between effectiveness and stability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the physical state parameter of the detergent composition from liquid to solid form. This parameter change creates a stable environment for the soil release polymer during storage, preventing chemical reactions with acid or oxidizer, while still allowing the polymer to function effectively for oily stain removal during the wash cycle.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If soil release polymer is used in final rinse step, then oily stain removal is improved, but polymer stability deteriorates in acidic environment

Engineering Contradiction:
Improveoily stain removal effectivenessVSAvoidpolymer stability during storage
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent extracts the soil release polymer from the acidic liquid sour environment and incorporates it into a solid detergent composition. This extraction protects the polymer from degradation during storage while maintaining its effectiveness for oily stain removal during the wash cycle.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent creates a composite solid detergent composition that combines the soil release polymer with other detergent ingredients in a stable matrix. This composite structure protects the polymer from chemical reactions during storage while allowing it to function effectively when the detergent is dissolved and applied to fabrics.

Inventive Principle:
Principle #40Composite materials

3Stability of the object's composition

If solid composition is formed through melting, casting, or pressing, then physical stability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvesolid composition stabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent utilizes phase transitions (melting and solidification) to form the solid detergent composition. By controlling the phase change of the composition during manufacturing, the patent achieves physical stability in the final product while using a relatively simple manufacturing process that doesn't require complex equipment or multiple steps.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solid composition effectively removes residual alkalinity and oily stains from synthetic fabrics, with the soil release polymer showing superior performance when used in the final rinse step, maintaining stability and increasing removal efficiency over multiple wash cycles.

Implementation Method 1

Synthetic fibers, (fabrics having synthetic fibers incorporated therein or made entirely of synthetic fibers), are hydrophobic and oleophilic. As such the oleophilic characteristics of the fiber permit oil and grime to be readily embedded in the fiber, and the hydrophobic properties of the fiber prevent water from entering the fiber to remove the contaminants from the fiber.

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Implementation Method 2

The polymers work by having both hydrophobic and hydrophilic blocks that allow them to adhere to the polyester surface and make it more hydrophilic. By making the surface more hydrophilic the affinity of oily soils, like dirty motor oil, with polyester is reduced which makes the soil easier to remove.

Methodology Applied
Scientific EffectHydrophilic interaction: Hydrophile

Implementation Method 3

Sour materials contain acid components that neutralize alkaline residues on the fabric.

Methodology Applied
Scientific EffectAcid-base neutralization: Chemical Bonding

Data Source

PatentUS10533147B2Soil release polymer in a solid sour
Publication Date: 2020.01.14 ECOLAB USA INC
  • US10533147B2 patent drawing
  • US10533147B2 patent drawing
  • US10533147B2 patent drawing

AI summary

Applicants have developed a physically and chemically stable solid composition containing a soil release polymer and an acidulant. The sour step thus accomplishes both stain removal and residual alkalinity removal. A novel method of using a soil release polymer and an acidulant together in the same post wash step of a laundry wash process is also disclosed. The solid composition is physically stable, even during aqueous dispensing, i.e. non-slumping and non-weeping. The solid could be formed through a melt, cast, or pressed process.