Solid State Battery Green Tape Lamination

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Solution Overview

Problem

Current Li-ion batteries using liquid electrolytes pose safety hazards due to flammability and reactivity, leading to potential fires and capacity imbalances in series stacking, which are addressed with costly safety measures that reduce energy density.

Innovation Solution

The development of solid state Li-ion batteries fabricated using a 'green tape' lamination and sintering process, where electrodes and separators are made from a mixture of active materials, conductive additives, and polymer binders, with a solid electrolyte, allowing for scalable and cost-effective high-volume manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If liquid electrolyte is used in Li-ion batteries, then ionic conductivity and electrochemical performance are improved, but safety hazards increase due to flammability and reactivity

Engineering Contradiction:
Improveionic conductivityVSAvoidsafety hazards
Core Design Contradiction:
Use of energy by moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent changes the physical state of the electrolyte from liquid to solid, fundamentally altering the safety properties while maintaining ionic conductivity through careful selection of solid electrolyte materials and optimization of their composition and structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite solid electrolyte materials combining multiple components to achieve both high ionic conductivity and enhanced safety, creating a material system that simultaneously addresses performance and safety requirements

Inventive Principle:
Principle #40Composite materials

2Reliability

If thick separators are used to prevent shorts in liquid electrolyte batteries, then safety is improved, but energy density decreases

Engineering Contradiction:
Improveshort preventionVSAvoidenergy density
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the electrolyte state to solid, which fundamentally alters the separator requirements and enables thinner separator designs that maintain safety while improving energy density

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts the electrolyte function from a separate liquid component and integrates it into the solid electrode structure itself, eliminating the need for thick separate separators

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If advanced separator structures with ceramic nano-particles are used, then short prevention is improved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improveshort preventionVSAvoidseparator structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the electrolyte to solid state, which simplifies the separator structure requirements and enables easier manufacturing while maintaining short prevention capabilities

Inventive Principle:
Principle #35Parameter changes

4Reliability

If safety elements and monitoring systems are added to liquid electrolyte batteries, then safety is improved, but energy density and cost decrease

Engineering Contradiction:
ImprovesafetyVSAvoidenergy density
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent extracts the safety function from separate monitoring systems and safety elements and integrates it into the solid electrolyte material itself, which inherently provides safety without requiring additional components

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The solid electrolyte material provides its own safety functions (flame resistance, dendrite prevention, thermal stability) without requiring external monitoring systems or safety additives, making the system self-protecting

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solid state batteries provide increased safety and higher energy density by eliminating flammable liquids, reducing the risk of fires, and enabling series stacking without capacity imbalances, thus enhancing reliability and efficiency.

Implementation Method 1

laminating together the green sheet of positive electrode material and the green sheet of separator material to form a laminated green stack

Methodology Applied
Scientific EffectLamination: Lamination

Implementation Method 2

sintering the laminated green stack to form a sintered stack comprising a positive electrode and a separator

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS11276886B2Solid state battery fabrication
Publication Date: 2022.03.15 ELEVATED MATERIALS US LLC
  • US11276886B2 patent drawing
  • US11276886B2 patent drawing
  • US11276886B2 patent drawing

AI summary

Embodiments of the invention generally relate to solid state battery structures, such as Li-ion batteries, methods of fabrication and tools for fabricating the batteries. One or more electrodes and the separator may each be cast using a green tape approach wherein a mixture of active material, conductive additive, polymer binder and/or solid electrolyte are molded or extruded in a roll to roll or segmented sheet/disk process to make green tape, green disks or green sheets. A method of fabricating a solid state battery may include: preparing and/or providing a green sheet of positive electrode material; preparing and/or providing a green sheet of separator material; laminating together the green sheet of positive electrode material and the green sheet of separator material to form a laminated green stack; and sintering the laminated green stack to form a sintered stack comprising a positive electrode and a separator.