All-Solid-State Battery Binder Composition for Stable Slurry Coating
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Solution Overview
Problem
Existing binder compositions for all-solid-state secondary batteries fail to achieve optimal viscosity and fluidity for slurry application, leading to poor battery characteristics and processability during production.
Innovation Solution
A binder composition comprising a polymer, an unsaturated acid metal salt monomer with a divalent metal, and a solvent, with a water content below 1,000 ppm, is used to create a slurry composition with improved dispersion stability and pressability, resulting in better battery characteristics and production processability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If a binder composition is added to achieve good battery characteristics, then battery performance is improved, but the viscosity and fluidity of the slurry composition become unsuitable for application
Solution Approach 1:
The invention changes the chemical composition parameters of the binder by specifying a polymer with carboxyl groups (0.1-10 mass%) and a metal salt of polybasic acid (0.01-5 mass%), which modifies the slurry's rheological properties to achieve both good battery characteristics and suitable viscosity for application
Solution Approach 2:
The invention uses a composite binder system combining polymer with carboxyl groups and metal salt of polybasic acid, creating a composite material that simultaneously provides adhesion for battery performance and controls viscosity for manufacturability
2Productivity
If the solid content concentration of the slurry composition is increased to improve productivity, then production efficiency is improved, but the dispersion stability deteriorates
Solution Approach 1:
The invention optimizes the concentration parameters of binder components (polymer 0.1-10 mass%, metal salt 0.01-5 mass%) to achieve a balance where high solid content (60-80 mass%) slurry maintains adequate dispersion stability while improving productivity
Data Source
AI summary
Provided are a binder composition for an all-solid-state secondary battery with which it is possible to obtain an all-solid-state secondary battery that has good battery characteristics and for which processability during all-solid-state secondary battery production is excellent, a slurry composition for an all-solid-state secondary battery that contains this binder composition for an all-solid-state secondary battery, a functional layer for an all-solid-state secondary battery that is formed from this slurry composition for an all-solid-state secondary battery, and an all-solid-state secondary battery that includes this functional layer for an all-solid-state secondary battery. The binder composition for an all-solid-state secondary battery contains a polymer, an unsaturated acid metal salt monomer, and a solvent. The unsaturated acid metal salt monomer includes a divalent metal.