Solid-State Layered Ion Sensor for Stable Concentration Measurement

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Solution Overview

Problem

Conventional ion concentration measurement methods using solid-state sensors face challenges such as high ion sensitivity, chemical instability, and temperature dependence due to the use of reference electrodes, leading to inaccurate measurements and potential damage to the measurement environment.

Innovation Solution

A sensor with a solid-state layered structure comprising a semiconductor layer, a gold and oxygen-containing layer separated by an insulation layer, which reduces ion sensitivity and enhances chemical and thermal stability, allowing for accurate ion concentration determination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional reference electrodes are used in solid-state ion concentration measurement, then ion concentration can be measured, but ion sensitivity is too high and chemical stability deteriorates

Engineering Contradiction:
Improveion concentration measurement accuracyVSAvoidchemical stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent extracts and removes the conventional reference electrode from the sensor system. Instead of using a traditional reference electrode with high ion sensitivity, the invention employs a solid-state sensor with a metal oxide layer that has deliberately reduced ion sensitivity, thereby eliminating the chemical instability and buffering issues associated with conventional reference electrodes while maintaining measurement functionality

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the ion sensitivity parameter of the reference electrode by using a metal oxide layer instead of conventional electrode materials. This parameter change reduces the ion sensitivity to an appropriate level, preventing the high ion sensitivity and chemical instability problems of traditional reference electrodes, while still enabling accurate ion concentration measurements through differential measurement

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If conventional reference electrodes are used in solid-state sensors, then ion concentration measurement is enabled, but temperature dependence increases

Engineering Contradiction:
Improveion concentration measurementVSAvoidtemperature dependence
Core Design Contradiction:
Measurement precisionVSTemperature

Solution Approach 1:

The patent removes the temperature-sensitive conventional reference electrode from the system and replaces it with a solid-state metal oxide-based sensor that exhibits reduced temperature dependence, thereby maintaining measurement capability while improving thermal stability

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a composite structure consisting of a semiconductor substrate with a metal oxide layer to create a reference electrode alternative that combines the advantages of solid-state stability with reduced temperature dependence, enabling reliable measurements across varying temperature conditions

Inventive Principle:
Principle #40Composite materials

3Measurement precision

If solid-state sensors with high ion sensitivity are used, then measurement sensitivity is improved, but chemical instability and measurement errors increase

Engineering Contradiction:
Improvemeasurement sensitivityVSAvoidchemical stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent applies local quality by creating a sensor system with two different solid-state sensors: one with higher ion sensitivity for measurement and one with reduced ion sensitivity as reference. This local differentiation in ion sensitivity allows the measurement sensor to maintain high sensitivity while the reference sensor provides stable baseline measurements, thereby resolving the contradiction between measurement sensitivity and chemical stability

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a copy of the solid-state sensor structure with modified properties (reduced ion sensitivity) to serve as a reference. This copied structure maintains the same solid-state stability and chemical resistance but with adjusted ion sensitivity, allowing differential measurement that eliminates the problem of high ion sensitivity causing chemical instability

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sensor achieves low ion sensitivity, improved chemical stability, and reduced measurement errors, enabling precise ion concentration measurements even in harsh environments.

Implementation Method 1

an insulation layer arranged between the first layer and the second layer

Methodology Applied
Scientific EffectInsulation: Dielectric

Data Source

PatentUS12571754B2Sensor having a solid-state layered structure, and method of producing a sensor
Publication Date: 2026.03.10 FRAUNHOFER GESELLSCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG EV
  • US12571754B2 patent drawing
  • US12571754B2 patent drawing
  • US12571754B2 patent drawing

AI summary

Sensor devices and systems having a solid-state layered structure and methods of producing the sensor devices and systems are described. In one embodiment, a sensor includes a first layer including a semiconductor material, a second layer including a gold material and an oxygen material, and an insulation layer arranged between the first and second layers.