Solid-State Laser Annealing for Semiconductor Film Crystallization

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Solution Overview

Problem

The existing laser annealing methods for manufacturing semiconductor films face challenges in achieving high crystalline quality using solid-state lasers, which have poor maintainability and high running costs, while excimer lasers offer high crystalline quality but at the expense of high maintenance and costs.

Innovation Solution

A method employing a solid-state laser that replicates the pulse waveform of an excimer laser by using two pulsed laser beams with the second beam having lower intensity than the first, ensuring the semiconductor film is not completely melted, maintaining a state with uniform crystal grain size and high crystalline quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If an excimer laser is used to crystallize an amorphous semiconductor film, then high crystalline quality is achieved, but running cost and maintenance cost increase

Engineering Contradiction:
Improvecrystalline qualityVSAvoidrunning cost
Core Design Contradiction:
Manufacturing precisionVSLoss of energy

Solution Approach 1:

The patent applies the copying principle by replicating the excimer laser's pulse waveform characteristics using a solid-state laser. The invention creates a copy of the excimer laser's temporal intensity profile (high intensity first pulse followed by lower intensity second pulse) using affordable solid-state laser technology, thereby achieving the same crystallization effect without the high running costs of excimer lasers.

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The patent applies parameter changes by modifying the temporal intensity parameters of the laser pulse. Specifically, it uses a two-pulse structure where the first pulse has higher intensity to initiate melting and the second pulse has lower intensity to control solidification, thereby achieving uniform crystal grain size and high crystalline quality while using cost-effective solid-state lasers.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If a solid-state laser is used to crystallize an amorphous semiconductor film, then running cost is reduced, but crystalline quality deteriorates

Engineering Contradiction:
Improverunning costVSAvoidcrystalline quality
Core Design Contradiction:
Loss of energyVSManufacturing precision

Solution Approach 1:

The patent applies periodic action by using a two-pulse laser irradiation sequence. The first pulse with higher intensity initiates the melting process, and the second pulse with lower intensity controls the solidification process. This periodic application of laser energy with specific timing and intensity ratios enables uniform crystallization and high crystalline quality using solid-state lasers.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent applies parameter changes by precisely controlling the temporal intensity parameters of the laser pulses. The first pulse uses higher intensity to achieve melting, while the second pulse uses lower intensity to control solidification rate, thereby achieving uniform crystal grain size and high crystalline quality that was previously only attainable with excimer lasers.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If a single high-intensity laser beam is used, then crystallization speed is improved, but crystal grain uniformity deteriorates

Engineering Contradiction:
Improvecrystallization speedVSAvoidcrystal grain uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies segmentation by dividing the single laser irradiation into two separate pulses with different intensity levels. The first pulse handles the melting function and the second pulse handles the solidification control function. This segmentation allows each pulse to perform its specific function optimally, achieving both fast crystallization and uniform crystal grain size.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies periodic action through the two-pulse irradiation sequence. The first pulse provides high-intensity energy for rapid melting and the second pulse provides lower-intensity energy for controlled solidification. This periodic energy input with optimized timing achieves both high crystallization speed and uniform crystal grain morphology.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the crystalline quality of semiconductor films while improving maintainability and reducing running costs, making it suitable for semiconductor film manufacturing.

Implementation Method 1

an amorphous semiconductor film formed over a substrate is irradiated with a laser beam to be crystallized, so that a polycrystalline semiconductor film is formed

Methodology Applied
Scientific EffectLaser heating and crystallization: Laser

Implementation Method 2

an amorphous semiconductor film formed over a substrate is irradiated with a laser beam to be crystallized

Methodology Applied
Scientific EffectPhase change from amorphous to crystalline: Phase Change

Implementation Method 3

irradiating an amorphous semiconductor film with a first pulsed laser beam emitted from a solid-state laser, and irradiating the semiconductor film with a second pulsed laser beam emitted from a solid-state laser and including intensity lower than that of the first pulsed laser beam

Methodology Applied
Scientific EffectMelting and solidification control: Melting

Data Source

PatentUS10991581B2Method for manufacturing semiconductor film
Publication Date: 2021.04.27 JSW AKTINA SYST CO LTD
  • US10991581B2 patent drawing
  • US10991581B2 patent drawing
  • US10991581B2 patent drawing

AI summary

A method for manufacturing a semiconductor film capable of forming a semiconductor film with high crystalline quality using a solid-state laser is provided. A method for manufacturing a semiconductor film according to the present disclosure includes the steps of (a) irradiating an amorphous semiconductor film with a first pulsed laser beam emitted from a solid-state laser, and then after the step (a), (b) irradiating the semiconductor film with a second pulsed laser beam including intensity lower than that of the first pulsed laser beam.