Solid Anaerobic Threadlocker Composition for Gap and Heat Resistance

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Solution Overview

Problem

Conventional liquid anaerobic threadlockers face challenges such as incomplete curing through large gaps, difficulty in curing exposed bondlines due to air exposure, and poor solvent resistance, leading to potential contamination and integrity issues.

Innovation Solution

An anaerobically curable composition comprising a liquid anaerobically curable component, a solid anaerobically curable component, a solid thermoplastic polyether polyurethane resin, and a curing component, which can be formulated into a solid form suitable for various applications, including tape or filament, providing a balanced threadlocking and adhesive performance with improved thermal resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If liquid anaerobic threadlockers are used, then they provide excellent threadlocking and sealing properties when cured, but they remain in liquid form until cured which causes handling difficulties and potential contamination

Engineering Contradiction:
Improvethreadlocking performanceVSAvoidhandling ease
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent changes the physical state parameter of the threadlocking composition from liquid to solid by incorporating wax and filler materials. This transformation maintains the anaerobic curing mechanism while improving handling characteristics, allowing the composition to be applied as a solid that melts or softens during application and then cures to a strong lock

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system combining anaerobically curable resin, wax, and filler materials. This composite approach allows the composition to exhibit solid-like handling properties while retaining the chemical reactivity needed for anaerobic curing, effectively merging the benefits of both liquid and solid forms

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional liquid anaerobic compositions are used, then they cure in the absence of oxygen, but they fail to cure properly when exposed to air at bondlines

Engineering Contradiction:
Improvecure completenessVSAvoidenvironmental tolerance
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent modifies the curing mechanism by introducing a dual-cure system that combines anaerobic curing with heat-activated curing. The composition contains initiators that respond to both anaerobic conditions and thermal energy, allowing the same material to cure effectively in either environment depending on which trigger is present

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention formulates a composite resin system that incorporates multiple initiator types and curing mechanisms. This composite approach enables the material to adapt to different environmental conditions, curing anaerobically when oxygen-excluded but also curing when heated, thus tolerating a broader range of application environments

Inventive Principle:
Principle #40Composite materials

3Reliability

If large gaps are present in threaded parts, then complete curing of the threadlocker is difficult, but using fillers may improve this

Engineering Contradiction:
Improvecure completeness in gapsVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent develops a composite formulation incorporating specific filler materials designed to improve flow and curing in gap applications. These fillers are selected and sized to facilitate penetration into gaps while maintaining the anaerobic curing mechanism, creating a multi-component system that addresses gap-curing challenges

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention utilizes filler materials with controlled porosity and surface characteristics that enhance the composition's ability to penetrate and cure in gap structures. The porous or surface-modified fillers provide pathways for the resin to flow into and throughout the gap region, ensuring complete curing even in challenging geometries

Inventive Principle:
Principle #31Porous materials

4Temperature

If thermal resistance is required at elevated temperatures, then the composition must maintain integrity, but conventional anaerobic threadlockers may degrade

Engineering Contradiction:
Improvethermal resistanceVSAvoidintegrity at temperature
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent formulates a high-temperature-resistant composite by selecting resin, wax, and filler materials specifically chosen for their thermal stability. This composite system maintains structural integrity and bonding strength at elevated temperatures where conventional anaerobic threadlockers would degrade, extending the operational temperature range

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention modifies the chemical composition parameters to enhance thermal resistance, using high glass transition temperature resins and thermally stable additives. These parameter changes shift the material's thermal performance characteristics, allowing it to withstand higher operating temperatures without losing mechanical properties or bonding strength

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves robust threadlocking and adhesive performance with breakaway torque values greater than 10 Nm and maintains integrity at elevated temperatures, ensuring effective bonding and resistance to environmental interactions.

Implementation Method 1

Anaerobically curable compositions are those which are stable in the presence of oxygen, but which polymerize in the absence of oxygen

Methodology Applied
Scientific EffectAnaerobic polymerization: Photopolymerisation

Implementation Method 2

Polymerization is initiated by the presence of free radicals, often generated from peroxy compounds

Methodology Applied
Scientific EffectFree radical generation:

Implementation Method 3

The compositions are thermally resistant at temperatures of at least 150° C.

Methodology Applied
Scientific EffectThermal resistance: Thermal Insulation

Data Source

PatentUS20240052219A1Anaerobically curable compositions
Publication Date: 2024.02.15 HENKEL KGAA
  • US20240052219A1 patent drawing
  • US20240052219A1 patent drawing
  • US20240052219A1 patent drawing

AI summary

An anaerobically curable composition comprising:a liquid anaerobically curable component;a solid anaerobically curable component;a solid polyether thermoplastic polyurethane resin; anda curing component for curing the anaerobically curable components.Advantageously, the compositions of the invention are substantially solid and may be used as threadlockers.