Solid Welding Wire Composition for Cryogenic Toughness at Lower Ni Cost

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Solution Overview

Problem

Current welding technologies for Ni alloy steel at low temperatures face challenges in reducing material costs while maintaining low temperature toughness and efficiency, particularly with Ni-based alloy welding materials that are expensive and prone to defects.

Innovation Solution

A solid wire with optimized chemical composition, including reduced Ni content and specific ratios of deoxidizing elements like Mn, Al, Ti, and Ta, is used for gas shielded arc welding, such as MIG or MAG, to achieve low oxygen content and improved toughness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If Ni-based alloy welding material is used to maintain low temperature toughness, then toughness at -196°C is improved, but material cost increases significantly

Engineering Contradiction:
Improvelow temperature toughnessVSAvoidmaterial cost
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent changes the chemical composition parameters by reducing Ni content from 60-80 mass% to 8-16 mass% and optimizing deoxidizing element contents (Mn: 0.05-1.80%, Al: 0.03-0.50%, Ti: 0-0.10%, Ta: 0-0.10%). This parameter optimization maintains low temperature toughness while significantly reducing material cost

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite welding material system combining reduced Ni content with optimized deoxidizing elements (Mn, Al, Ti, Ta) to achieve both cost reduction and performance maintenance. The synergistic combination of these elements compensates for reduced Ni content

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If Ni content in welding material is reduced to match Ni alloy steel level, then material cost is reduced, but oxygen content must be reduced to extremely low level to maintain toughness

Engineering Contradiction:
Improvematerial costVSAvoidoxygen content control
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent applies preliminary deoxidation by adding deoxidizing elements (Mn, Al, Ti, Ta) to the welding material composition before welding. This preliminary action reduces oxygen content in the weld metal, eliminating the need for extremely precise oxygen control during welding and enabling use of more efficient welding methods

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The deoxidizing elements (Mn, Al, Ti, Ta) act as intermediaries that react with oxygen to form oxides, thereby removing oxygen from the weld metal. This intermediary mechanism achieves low oxygen content without requiring extremely precise control

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If TIG welding is used to reduce oxygen content in weld metal, then low temperature toughness is improved, but welding efficiency decreases

Engineering Contradiction:
Improvelow temperature toughnessVSAvoidwelding efficiency
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent uses consumable solid wire welding materials containing deoxidizing elements that provide oxygen removal functionality. This disposable approach to oxygen control enables use of more efficient MIG/MAG welding methods instead of TIG welding, improving welding efficiency

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Productivity

If MAG welding is used to improve welding efficiency, then welding cost is reduced, but oxygen is easily incorporated into weld metal

Engineering Contradiction:
Improvewelding efficiencyVSAvoidoxygen incorporation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent applies preliminary deoxidation by incorporating deoxidizing elements (Mn, Al, Ti, Ta) into the welding material composition before welding. This preliminary action prevents oxygen incorporation issues during MAG welding, enabling use of this efficient welding method

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent converts the harmful effect of oxygen incorporation during MAG welding into a benefit by using deoxidizing elements that react with oxygen to form oxides. This transforms the oxygen problem into an opportunity to achieve low oxygen content weld metal while maintaining high welding efficiency

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces welding material costs and enhances low temperature toughness of weld metals, achieving high efficiency and low cost production of welds with excellent tensile strength and Charpy absorbed energy at -196°C.

Implementation Method 1

a solid wire with optimized chemical composition, including reduced Ni content and specific ratios of deoxidizing elements like Mn, Al, Ti, and Ta, is used for gas shielded arc welding, such as MIG or MAG, to achieve low oxygen content and improved toughness

Methodology Applied
Scientific EffectDeoxidation: Redox Reactions

Implementation Method 2

gas shielded arc welding, such as MIG or MAG

Methodology Applied
Scientific EffectGas shielding:

Data Source

PatentEP3812085B1Solid wire and method of manufacturing welded joint
Publication Date: 2024.04.03 NIPPON STEEL CORPORATION
  • EP3812085B1 patent drawingFigure 1~2
  • EP3812085B1 patent drawing
  • EP3812085B1 patent drawing

AI summary

A solid wire according to an aspect of the present invention contains, as a chemical composition: C: 0.003% to 0.080%; Si: 0.0010% to 0.50%; Mn: 0.050% to 1. 80%; Al: 0.030% to 0.500%; Ni: 8.0% to 16.0%; P: 0.0200% or less; S: 0.0100% or less; O: 0.050% or less; Ta: 0% to 0.1000%; Cu: 0% to 0.5%; Cr: 0% to 0.5%; Mo: 0% to 0.5%; V: 0% to 0.20%; Ti: 0% to 0.10%; Nb: 0% to 0.10%; B: 0% to 0.010%; Mg: 0% to 0.80%; REM: 0% to 0.050%; and a remainder: Fe and impurities, α is 1.35% to 5.50%, and Ceq is 0.250% to 0.520%.