Solubilized Polymer Concentrates for Oil-Based Drilling Fluids

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Solution Overview

Problem

Oil-based well drilling and servicing fluids face significant fluid loss issues due to their inability to effectively prevent migration into subterranean formations, leading to inefficiencies and potential formation damage, especially when using polymeric additives that are difficult to dissolve in low-aromatic hydrocarbon oils.

Innovation Solution

The development of a polymeric composition and method involving an oil-soluble polymer and an organophilic polyphenolic fluid loss control agent, dissolved and dispersed in an aromatic-free paraffinic hydrocarbon oil, to form concentrates that are added to oil-based muds to reduce fluid loss, with specific mixing conditions to ensure solubility and effectiveness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polymeric additives are used to control fluid loss in oil-based drilling fluids, then fluid loss control is improved, but the additives are difficult to dissolve in low-aromatic hydrocarbon oils

Engineering Contradiction:
Improvefluid loss controlVSAvoidsolubility of polymeric additives
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters of the base oil by incorporating aromatic hydrocarbons (such as trimethylbenzene) into the low-aromatic hydrocarbon base. This parameter change enables the polymeric additives to dissolve effectively while maintaining overall low aromatic content, thus resolving the contradiction between solubility and fluid loss control effectiveness.

Inventive Principle:
Principle #35Parameter changes

2Loss of substance

If conventional fluid loss control additives are used, then some fluid loss reduction is achieved, but unacceptable high losses continue to fractures and porous structures

Engineering Contradiction:
Improvedrilling fluid lossVSAvoideffectiveness in high loss formations
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The patent employs a composite fluid loss control system combining multiple components: polymeric additives (such as styrene-butadiene copolymer), organophilic clay viscosifier, and aromatic hydrocarbon solvents. This composite approach creates a multi-functional system that addresses both viscous and porous formation losses simultaneously, overcoming the limitations of single-component additives.

Inventive Principle:
Principle #40Composite materials

3Productivity

If oil-based drilling fluids are used to lubricate drilling tools and remove cuttings, then drilling operations are enabled, but substantial amounts of fluid are lost to formations

Engineering Contradiction:
Improvedrilling operation efficiencyVSAvoiddrilling fluid loss to formation
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent applies fluid loss control additives to the drilling fluid before it contacts the formation. The polymeric additives and organophilic clay are pre-mixed and solubilized in the base oil, creating a prepared system that forms protective filter cakes at the wellbore interface. This preliminary action prevents fluid loss before substantial formation damage can occur, maintaining productivity while reducing losses.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces fluid loss in oil-based muds, maintaining fluid efficiency and preventing formation damage by ensuring the additives are fully soluble and effective, even at elevated temperatures, thereby enhancing the stability and performance of drilling and servicing operations.

Implementation Method 1

an oil-soluble polymer and an organophilic polyphenolic fluid loss control agent, dissolved and dispersed in an aromatic-free paraffinic hydrocarbon oil, to form concentrates

Methodology Applied
Scientific EffectSolubility: Solvation

Implementation Method 2

an oil-soluble polymer and an organophilic polyphenolic fluid loss control agent, dissolved and dispersed in an aromatic-free paraffinic hydrocarbon oil

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

Most subterranean wells are drilled with the intent of forming a filter cake of varying thickness on the sides of the borehole. The primary purpose of the filter cake is to reduce the large losses of drilling fluid to the surrounding formation.

Methodology Applied
Scientific EffectFilter cake formation: Deposition (physical)

Data Source

PatentUS10563111B2Solubilized polymer concentrates, methods of preparation thereof, and well drilling and servicing fluids containing the same
Publication Date: 2020.02.18 TUCC TECHNOLOGY LLC

AI summary

The invention provides concentrates for reducing the fluid loss on an oil base well drilling or servicing fluid, the concentrates comprising an oleagineous liquid and (1) a polymer which is solublized in the oleagineous liquid, or (2) a polymer which is solublized in the oleaginous liquid together with an organophilic polyphenolic material which is solublized and/or dispersed in the oleagineous liquid. The method of preparing the concentrate and the method of reducing the fluid loss of an oil base well drilling or servicing fluid utilizing the concentrates is also disclosed. The preferred oil soluble polymer is a styrene-butadiene rubber crumb. The preferred oleagineous liquid is an aromatic-free hydrogenated oil essentially containing only saturated hydrocarbons. The preferred polyphenolic material is a source of humic acid, such as mined lignite.