Solvent-Based Ink Composition for Piezoelectric Inkjet Ejection Stability

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Solution Overview

Problem

Existing solvent-based ink compositions face challenges in achieving stable ejection, particularly when used in high-frequency and high-speed piezoelectric ink jet methods, due to aggregation and interference of metal particles, which affect glossy properties and ejection stability.

Innovation Solution

A solvent-based ink composition incorporating an organic solvent, surface-treated metal powder with aluminum or aluminum alloy, and a polyoxyethylene alkyl ether phosphoric acid compound, where the compound content is between 0.1 to 10.0% by mass, and the metal powder is treated with a fluorine-based surface agent, enhancing dispersion stability and suppressing particle interference.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the average particle diameter of metal particles is decreased, then ejection stability is improved, but glossy property of the coating film deteriorates

Engineering Contradiction:
Improveejection stabilityVSAvoidglossy property
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent applies parameter changes by optimizing the average particle diameter of metal particles to a specific range (0.5 μm to 5 μm) and controlling the particle size distribution (specifically, limiting particles larger than 10 μm to 10% or less by number). This parameter optimization resolves the contradiction by finding the optimal balance point where ejection stability is sufficiently improved while glossiness is preserved.

Inventive Principle:
Principle #35Parameter changes

2Shape

If flaky shaped metal particles are used, then glossy property is improved, but ejection defect increases due to high anisotropic property

Engineering Contradiction:
Improveglossy propertyVSAvoidejection stability
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent controls the aspect ratio of flaky metal particles within a specific range (1.05 to 3.0) to manage anisotropy. By limiting the aspect ratio, the patent reduces ejection defects caused by high anisotropic properties while still maintaining sufficient glossiness from the flaky shape. This parameter control resolves the contradiction between glossiness and ejection stability.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If metal particles are processed into highly fine particles, then ejection stability is improved, but aspect ratio decreases leading to poor glossy property

Engineering Contradiction:
Improveejection stabilityVSAvoidaspect ratio
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent optimizes the average particle diameter to 0.5 μm to 5 μm, avoiding excessive fineness that would reduce aspect ratio. This parameter setting ensures that metal particles maintain sufficient aspect ratio for glossy properties while being fine enough to achieve stable ejection. The controlled particle size prevents the degradation of aspect ratio that occurs with highly fine particles.

Inventive Principle:
Principle #35Parameter changes

4Shape

If a fluorine-based surface treating agent is used, then glossy state is improved, but compatibility with organic solvent decreases leading to poor dispersibility

Engineering Contradiction:
Improveglossy stateVSAvoiddispersibility
Core Design Contradiction:
ShapeVSStability of the object's composition

Solution Approach 1:

The patent uses a composite surface treatment approach by combining a fluorine-based surface treating agent with a specific organic solvent system. The fluorine-based agent provides glossy state while the carefully selected organic solvent (with specific physical properties including viscosity of 0.2 to 5.0 cP and surface tension of 15 to 40 mN/m) ensures good compatibility and dispersibility. This composite approach resolves the contradiction between glossiness and dispersibility.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved ejection stability and glossy properties, maintaining stability even under high-frequency and high-speed conditions, while ensuring compatibility with organic solvents and preventing particle aggregation.

Implementation Method 1

a polyoxyethylene alkyl ether phosphoric acid compound... suppressing particle aggregation

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

When the surfaces of the metal particles are processed using a hydrophobic surface treating agent, the surface free energy of the metal particles is decreased... a highly glossy state can be maintained

Methodology Applied
Scientific EffectSurface free energy reduction: Surface Tension

Implementation Method 3

in a process in which the gloss is gradually obtained while an organic solvent contained in the ink composition is dried or adsorbed

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS11370930B2Solvent-based ink composition
Publication Date: 2022.06.28 SEIKO EPSON CORP
  • US11370930B2 patent drawing
  • US11370930B2 patent drawing
  • US11370930B2 patent drawing

AI summary

A solvent-based ink composition is provided that includes: an organic solvent; a surface-treated metal powder; and a polyoxyethylene alkyl ether phosphoric acid compound, the content of the polyoxyethylene alkyl ether phosphoric acid compound with respect to the total mass of an ink is 0.1 to 10.0 percent by mass, and the surface-treated metal powder contains aluminum or an aluminum alloy and is surface-treated by a surface treating agent of a fluorine-based compound.