Solvent Deasphalting for Heavy Oil Viscosity Reduction

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Solution Overview

Problem

The processing of heavy oils and bitumens is hindered by their high viscosity, presence of salts, metals, and organic acids, requiring expensive diluents for transportation and complex refining steps, which increases capital investment and operating expenses.

Innovation Solution

A process that dilutes heavy oils or bitumens with a hydrocarbon diluent for transport to a solvent deasphalting unit, where the diluent is also used as a solvent, allowing for integrated asphaltene separation and water recovery, eliminating the need for front-end desalting and fractionation, and operating at moderate temperatures to reduce equipment costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If heavy oils or bitumens are transported by traditional means, then transportation is possible, but high viscosity requires expensive hydrocarbon diluents and additional transport costs

Engineering Contradiction:
Improvetransportation of heavy oilVSAvoidamount of diluent required
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The patent extracts and removes asphaltenes from the heavy oil feedstock using solvent deasphalting before transportation. By removing the problematic asphaltene fraction that causes high viscosity, the remaining deasphalted oil can be transported more easily without requiring expensive hydrocarbon diluents, thus solving the transportation problem while reducing diluent quantity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent performs preliminary solvent deasphalting and water removal before the transportation stage. By conducting these upgrading operations in advance at the well site or production facility, the oil is pre-treated to remove viscosity-increasing components, enabling easier and more economical subsequent transportation without diluent

Inventive Principle:
Principle #10Preliminary action

2Reliability

If front-end desalting and fractionation are performed, then salt and water are removed, but capital investment and operating expenses increase

Engineering Contradiction:
Improvequality of processed oilVSAvoidnumber of processing units
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges multiple processing functions into a single integrated solvent deasphalting unit. This unit simultaneously performs desalting, dewatering, and asphaltene separation in one operation, eliminating the need for separate front-end desalting and fractionation units, thus reducing device complexity while maintaining reliable oil quality

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The solvent deasphalting unit is designed to perform multiple functions: removing asphaltenes, separating water, and eliminating salts all in one process step. This multi-functional approach replaces what would traditionally require multiple specialized units, reducing overall plant complexity while ensuring high-quality processed oil

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of operation

If elevated temperatures are used to maintain flowability, then heavy oil remains pumpable, but energy consumption increases and equipment corrosion worsens

Engineering Contradiction:
Improveflowability of heavy oilVSAvoidenergy for heating and pumping
Core Design Contradiction:
Ease of operationVSUse of energy by moving object

Solution Approach 1:

The patent removes asphaltenes through solvent deasphalting, which fundamentally changes the rheological properties of the remaining oil. The deasphalted oil has lower viscosity and better flow characteristics, eliminating the need for elevated temperature maintenance during transportation and reducing energy consumption for heating and pumping

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameter of the heavy oil by removing asphaltenes, which transforms its physical properties. The resulting deasphalted oil has improved flowability at ambient temperatures, allowing transportation without thermal energy input, thus reducing energy use and preventing thermal degradation and corrosion issues

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If salts are vaporized to meet pipeline specifications, then water content is reduced, but salts remain in the oil and increase transportation problems

Engineering Contradiction:
Improvewater content in oilVSAvoidsalt content in transported oil
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent uses solvent deasphalting to extract and remove salts from the heavy oil feedstock. The salts are separated into the asphaltene fraction or aqueous phase during the solvent extraction process, effectively eliminating them from the deasphalted oil before transportation, thus solving both water content and salt content issues simultaneously

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies processing, reduces capital investment, decreases operating expenses, and enhances the reliability of heavy oil or bitumen upgrading by integrating solvent deasphalting and water recovery, while minimizing the need for high-alloy metals and expensive metallurgy.

Implementation Method 1

solvent deasphalting the mixture to recover an asphaltene fraction, a deasphalted oil fraction essentially free of asphaltenes, and a solvent fraction comprising the diluent

Methodology Applied
Scientific EffectSolvent extraction: Liquid-Liquid Extraction

Implementation Method 2

The upgraded heavy oil or bitumen can be pipelined to a water removal unit, which can operate by decantation, phase separation, or other means

Methodology Applied
Scientific EffectPhase separation: Density Gradient

Data Source

PatentEP2166063B1Bitumen production-upgrade with solvents
Publication Date: 2015.10.14 KELLOGG BROWN & ROOT INC
  • EP2166063B1 patent drawingFigure 1
  • EP2166063B1 patent drawingFigure 2
  • EP2166063B1 patent drawingFigure 3

AI summary

Disclosed is a process for the upgrading of heavy oils and bitumens, where the total feed to the process can include heavy oil or bitumen, water, and diluent. The process can include the steps of solvent deasphalting 110 the total feed 105 to recover an asphaltene fraction 116, a deasphalted oil fraction 118 essentially free of asphaltenes, a water fraction 112, and a solvent fraction 114. The process allows removal of salts from the heavy oils and bitumens either into the aqueous products or with the asphaltene product.