Solvent-Free PU Slurry for UV-Cured Protective Glove Coatings
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Current polyurethane (PU) gloves on the market face issues with residual toxic solvents from solvent-based production, leading to health and environmental hazards, while water-based PU gloves lack wear resistance and oil resistance, and are costly.
Innovation Solution
A solvent-free PU slurry composed of specific components A and B, which are mixed and cured under UV irradiation to produce gloves with enhanced wear and oil resistance, eliminating harmful residues and reducing production costs.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If solvent-based PU is used to produce protective gloves, then wear resistance, oil resistance, and solvent resistance are improved, but toxic DMF solvent residues remain in the gloves causing harm to human body and environment
Solution Approach 1:
The patent changes the fundamental parameter of the slurry composition from solvent-based to solvent-free. By using a two-component system where component A (polyol mixture) and component B (prepolymer) react upon mixing to form PU foam in situ, the patent eliminates the need for DMF solvent while achieving the desired mechanical properties through controlled foam cell structure and crosslinking density
Solution Approach 2:
The patent utilizes phase transition of the polyol mixture during the reaction process. When component A and component B are mixed, the exothermic reaction causes localized heating and phase changes that lead to foam formation. The controlled phase transition from liquid to foam structure creates the desired cellular morphology that provides both wear resistance and eliminates solvent residues
2Object-affected harmful factors
If water-based PU emulsion is used to produce protective gloves, then harmful solvent residues are reduced, but wear resistance, oil resistance, and solvent resistance deteriorate
Solution Approach 1:
The patent changes the dispersion medium parameter from water-based emulsion to solvent-free composition. By eliminating water as a solvent and using a two-component reactive system that forms PU foam in situ, the patent achieves both environmental friendliness (no harmful residues) and improved mechanical properties (superior wear, oil, and solvent resistance compared to water-based gloves)
3Strength
If solvent-based PU production process is used, then wear resistance is improved, but production cost increases due to toxic solvent requirements and multiple immersing and washing steps
Solution Approach 1:
The patent extracts and eliminates the toxic DMF solvent from the production process entirely. By using a solvent-free two-component system that cures in situ, the patent removes the need for multiple immersing and washing steps required in conventional solvent-based processes, thereby reducing production costs while maintaining or improving wear resistance
Solution Approach 2:
The patent enables the slurry to self-cure and self-foam upon mixing of components A and B. The exothermic reaction between isocyanate and polyol groups provides self-heating that drives foam formation and curing without external energy input, eliminating the need for complex drying ovens and washing facilities, thereby simplifying the production process and reducing costs
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solvent-free PU slurry results in gloves with superior wear and oil resistance, no harmful residues, and a simplified production process at lower costs, addressing the limitations of existing PU glove technologies.
Implementation Method 1
mixing the mixture system with the photoinitiator and the delayed-action catalyst to obtain the component A; coating an anti-penetration agent on a surface of the glove core, subjecting a resulting coated glove core to impregnating with the solvent-free PU slurry, ultraviolet (UV)-curing
Data Source
AI summary
Provided are a solvent-free polyurethane (PU) slurry and a preparation method thereof, and environmental-friendly resin-coated protective gloves and a preparation method thereof. The solvent-free PU slurry does not have an organic solvent, and the reaction speed and efficiency of a component A and a component B are controlled by adjusting the type and dosage of raw materials. When preparing the protective gloves, the slurry can be cured instantly under ultraviolet (UV) irradiation to greatly improve a number average molecular weight and a cross-linking density of polymers in the protective gloves produced from the solvent-free PU slurry, thereby improving wear resistance, oil resistance, and solvent resistance of the protective gloves produced from the solvent-free PU slurry.


