Solvent-Free Quantum Dot Composition for Stable Ink-Jetting

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Solution Overview

Problem

Existing quantum dot compositions face challenges with viscosity issues due to solvent limitations, leading to nozzle clogging and reduced photoefficiency, making it difficult to apply them in actual processes.

Innovation Solution

A solvent-free curable composition is developed, incorporating a curable monomer with a linking group and quantum dots, which maintains low viscosity and improves ink-jetting properties, ensuring excellent storage stability and processability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If quantum dots are dispersed in a solvent with high hydrophobicity to achieve good dispersion, then the quantum dots can be stably dispersed, but the viscosity increases excessively and processability deteriorates

Engineering Contradiction:
Improvequantum dot dispersion stabilityVSAvoidprocessability
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent changes the chemical parameters of the curable monomer by introducing a linking group with specific substituents (R1-R10 groups) to modify the monomer's polarity and viscosity characteristics, enabling better quantum dot dispersion without excessive viscosity increase

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite curable monomer system combining the linking group structure with quantum dots, where the composite material exhibits both good dispersion properties and acceptable viscosity for ink-jetting processes

Inventive Principle:
Principle #40Composite materials

2Reliability

If the quantum dot content is increased to improve photoefficiency, then photoefficiency increases, but the viscosity exceeds the ink-jetting range and processability is lost

Engineering Contradiction:
ImprovephotoefficiencyVSAvoidink-jetting processability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent modifies the curable monomer's molecular structure parameters (introducing linking groups with specific R1-R10 substituents) to change the composition's rheological properties, allowing higher quantum dot loading while maintaining ink-jetting suitable viscosity

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If a solvent is used to reduce viscosity for ink-jetting, then viscosity is improved, but nozzle drying and nozzle clogging occur during the process

Engineering Contradiction:
Improveviscosity for ink-jettingVSAvoidnozzle stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent extracts and eliminates the solvent component from the composition entirely, using a solvent-free curable monomer system that achieves appropriate viscosity through the monomer's molecular structure itself rather than through dissolved solvent

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the fundamental composition parameters from a solvent-based system to a solvent-free system, where the curable monomer's intrinsic properties (modified by the linking group structure) provide the necessary viscosity characteristics without the harmful effects of solvent volatilization

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solvent-free composition achieves stable ink ejection and maintains quantum dot efficiency, minimizing nozzle clogging and thickness deviations, enabling effective application in display devices.

Implementation Method 1

a curable monomer having a linking group and used for producing a cured film

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS12410365B2Solvent-free curable composition, cured film produced using same composition, color filter comprising same cured film, and display device
Publication Date: 2025.09.09 SAMSUNG SDI CO LTD
  • US12410365B2 patent drawing
  • US12410365B2 patent drawing
  • US12410365B2 patent drawing

AI summary

Disclosed are a solvent-free curable composition including quantum dots; and a curable monomer represented by Chemical Formula 1, a cured layer manufactured using the composition, a color filter including the cured layer, and a display device including the color filter.In Chemical Formula 1, each substituent is as defined in the specification.