Skin Coating Film Formation Through Solvent-Driven Phase Separation

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Solution Overview

Problem

Existing cosmetic methods using inorganic fine particles to scatter or reflect light on the skin often result in uneven distribution, making skin imperfections more noticeable and leading to makeup deterioration due to particle migration and deformation with facial expressions.

Innovation Solution

A coating film is formed using a liquid composition containing solvents A and B with specific Hansen solubility parameters and a polymer C, where solvent A has a boiling point below 99°C and solvent B above 150°C, and polymer C is soluble in A but insoluble in B, forming primary particles with a core-shell structure that scatter light and provide elasticity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If inorganic fine particles are used to scatter or reflect light on the skin, then the appearance of skin unevenness is improved, but the particles become unevenly distributed and migrate, making skin imperfections more noticeable and causing makeup deterioration

Engineering Contradiction:
Improvelight scattering effectVSAvoidmakeup durability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent changes the physical and chemical parameters of the coating material by using a polymer with specific solubility characteristics (soluble in solvent A, insoluble in solvent B) and controlling solvent evaporation rates. This transforms the particle distribution mechanism from passive settling to active control during drying, preventing migration while maintaining light scattering properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transition of the solvent system during evaporation. By employing two solvents with different boiling points and solubility parameters, the coating undergoes controlled phase separation during drying, forming stable primary particles that prevent makeup deterioration while maintaining the desired optical effects

Inventive Principle:
Principle #36Phase transitions

2Illumination intensity

If inorganic fine particles are applied to the skin, then light scattering is achieved, but the particles deform with facial expressions, leading to makeup deterioration

Engineering Contradiction:
Improvelight scatteringVSAvoidparticle position stability
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent creates a composite coating system where polymer particles are dispersed in a specific solvent combination. This composite structure allows the coating to adapt to facial expressions while maintaining particle position stability, as the polymer matrix provides elasticity and the controlled solvent evaporation prevents particle migration during skin movement

Inventive Principle:
Principle #40Composite materials

3Reliability

If a coating film is formed using specific solvent combinations and polymers, then particle migration is prevented and makeup durability is enhanced, but the formulation complexity increases

Engineering Contradiction:
Improvemakeup durabilityVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent establishes specific parameter ranges for the solvents (boiling points, Hansen solubility parameters) and polymer properties to achieve optimal performance. By defining these parameters precisely, the formulation achieves stable particle distribution and prevented migration while providing clear guidelines for reproduction, managing complexity through standardization

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves excellent concealment of skin unevenness and enhances makeup durability by preventing particle migration and maintaining film integrity despite facial deformations.

Implementation Method 1

a boiling point of the solvent A is lower than 99° C.

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

the solvent B is compatible with the solvent A, and the polymer C is soluble in the solvent A but insoluble in the solvent B

Methodology Applied
Scientific EffectPhase separation:

Implementation Method 3

a distance Ra of the Hansen solubility parameter of the solvent A to water as expressed by the following equation (1) is 36 or less

Methodology Applied
Scientific EffectHansen solubility parameter: Solvation

Implementation Method 4

there have been made attempts to scatter or reflect incident light on the skin by blending spherical or plate-like inorganic fine particles

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 5

a method for forming a coating film including a step of coating a liquid composition I containing a solvent A, a solvent B, and a polymer C to skin

Methodology Applied
Scientific EffectFilm formation:

Data Source

PatentUS12419819B2Method for forming coating film
Publication Date: 2025.09.23 KAO CORP
  • US12419819B2 patent drawing
  • US12419819B2 patent drawing
  • US12419819B2 patent drawing

AI summary

The present invention relates to a method for forming a coating film including a step of coating a liquid composition I containing a solvent A, a solvent B, and a polymer C to skin, wherein a boiling point of the solvent A is lower than 99° C., and a distance Ra of the Hansen solubility parameter of the solvent A to water is 36 or less; a boiling point of the solvent B is 150° C. or higher, and a distance Ra of the Hansen solubility parameter of the solvent B to water is 40 or more; and the solvent B is compatible with the solvent A, and the polymer C is soluble in the solvent A but insoluble in the solvent B.