Solventless Polyurethane Coating for Carbon Nanotube Conductivity

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Solution Overview

Problem

Carbon nanotube (CNT) networks used for electrically conductive applications, such as aerospace coatings, face significant resistance changes when exposed to solvents in typical topcoats, leading to conductivity loss and potential failure in resistive heating operations.

Innovation Solution

A solventless polyurethane coating composition with isocyanate crosslinking agents is applied directly to the CNT network, maintaining electrical conductivity and providing mechanical and chemical durability, preventing subsequent coatings from disrupting the CNT network's conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a solventless polyurethane coating is applied to maintain CNT conductivity, then the electrical conductivity is preserved, but the chemical resistance to environmental hazards may be reduced compared to conventional topcoats

Engineering Contradiction:
Improveelectrical conductivityVSAvoidchemical resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The solution employs a composite coating system where solventless polyurethane is combined with other functional layers. This composite approach allows the polyurethane to provide conductivity preservation while complementary layers enhance chemical resistance to environmental hazards

Inventive Principle:
Principle #40Composite materials

2Reliability

If multiple coating layers are added to provide comprehensive protection, then the durability and environmental resistance are improved, but the complexity of the coating system increases

Engineering Contradiction:
ImprovedurabilityVSAvoidcoating system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The solventless polyurethane coating is designed to perform multiple functions simultaneously: it provides mechanical durability, chemical resistance, and serves as a compatible base for subsequent topcoats. This multi-functionality reduces the need for separate specialized layers, simplifying the overall coating system

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solventless coating maintains the CNT network's conductivity, with sheet resistance changes of 81% or less, ensuring the CNTs' electrical properties are preserved, and the coating provides sufficient chemical resistance to environmental hazards, enhancing the durability and performance of CNT-based aerospace applications.

Implementation Method 1

A method of making a layered CNT-containing composition comprises: providing a CNT layer that is disposed on a substrate; and applying a solventless polymer precursor directly onto the CNT layer.

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

the coating provides sufficient chemical resistance to environmental hazards, enhancing the durability and performance of CNT-based aerospace applications

Methodology Applied
Scientific EffectChemical Resistance:

Data Source

PatentUS11499058B2Solventless coated carbon nanotube network
Publication Date: 2022.11.15 BATTELLE MEMORIAL INST
  • US11499058B2 patent drawing
  • US11499058B2 patent drawing

AI summary

A method of coating a carbon nanotube material with a solventless coating composition is described. The resulting coating has been shown to preserve the conductivity of the conductive layer and protect the conductive layer from the effects of subsequent coating compositions. Examples are shown in which the coating formulation comprises a polyol and an isocyanate. A layer material comprising a polyurethane coating on a carbon nanotube network layer is also described.