Continuous Sono-Chemical Reactor for Biodiesel

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Solution Overview

Problem

Current biodiesel production through transesterification is a slow process, and existing ultrasonic reactors are either too large, expensive, or limited in processing volume, making them unsuitable for small-scale, cost-effective, and efficient biodiesel production from waste oils.

Innovation Solution

The development of continuous sono-chemical reactors with multiple sections, including a sono-reactor section for acoustic energy concentration, a static mixer section for passive mixing, and a product separation section for efficient phase separation, allowing continuous flow and reducing reactant residence time, thereby enhancing reaction rates and product yield.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If traditional transesterification reaction is used for biodiesel production, then the process is simple to operate, but the reaction rate is slow

Engineering Contradiction:
Improveease of operationVSAvoidreaction rate
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent applies ultrasonic vibration to the reactant mixture, generating cavitation bubbles that implode and create localized high-energy zones. This mechanical vibration dramatically accelerates the transesterification reaction rate while maintaining operational simplicity through continuous flow processing.

Inventive Principle:
Principle #18Mechanical vibration

Solution Approach 2:

The ultrasonic cavitation process induces phase transitions through bubble formation and collapse, creating extreme local conditions (high temperature and pressure) that accelerate the chemical reaction. The continuous flow system maintains steady-state phase transitions for sustained high reaction rates.

Inventive Principle:
Principle #36Phase transitions

2Quantity of substance

If high power ultrasound devices are used to process large volumes of fluid, then the processing volume increases, but the power consumption increases

Engineering Contradiction:
Improveprocessing volumeVSAvoidpower consumption
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The reactor is divided into multiple sections (sono-reactor section, static mixer section, product separation section) that process fluid sequentially. This segmentation allows distributed ultrasonic energy application, where each section handles a portion of the total flow, reducing the power required per unit volume while maintaining high overall processing capacity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The continuous flow system ensures that ultrasonic energy is applied continuously to fresh reactant mixture throughout the process, eliminating idle time and maximizing energy utilization efficiency. The steady-state operation maintains optimal cavitation conditions without the energy losses associated with batch processing.

Inventive Principle:
Principle #20Continuity of useful action

3Productivity

If ultrasonic flow cells are used for sonicating flowing fluid, then the reaction rate increases, but the processing volume is limited

Engineering Contradiction:
Improvereaction rateVSAvoidprocessing volume
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent merges the ultrasonic sonication function with continuous flow mixing and product separation in an integrated reactor system. The sono-reactor section combines ultrasonic energy application with reactant mixing, while the downstream static mixer and separation sections continue the process, achieving both high reaction rates and large processing volumes through functional integration.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The reactor design transitions from confined ultrasonic flow cells to an expanded continuous flow system with multiple spatial zones. By adding the dimensional aspect of continuous flow through the reactor sections, the system maintains the high reaction rates of ultrasonic processing while dramatically increasing the volume of fluid that can be processed.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

4Productivity

If multiple reactor sections are added for continuous processing, then the processing efficiency increases, but the device complexity increases

Engineering Contradiction:
Improveprocessing efficiencyVSAvoiddevice complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The reactor is segmented into three distinct functional sections (sono-reactor, static mixer, product separation), each performing a specific operation. This segmentation allows for modular design and construction, where each section can be optimized independently while maintaining overall system simplicity through clear functional separation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each reactor section serves multiple purposes: the sono-reactor section performs both ultrasonic treatment and initial mixing, the static mixer section continues mixing while beginning separation, and the product separation section completes both separation and product collection. This multi-functionality reduces the need for additional dedicated components, maintaining device simplicity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The continuous sono-chemical reactors facilitate faster reaction rates and reduced costs by concentrating acoustic energy, maximizing space usage, and efficiently separating products, leading to increased biodiesel production efficiency and cost-effectiveness, especially for small-scale applications.

Implementation Method 1

Ultrasound may generate millions of micro level cavitation bubbles, which cause tremendous increase in mass transfer upon implosion. This phenomenon may increase the reaction rate in a localized zone by several orders of magnitude.

Methodology Applied
Scientific EffectAcoustic cavitation: Acoustic Cavitation

Implementation Method 2

a static mixer section that is configured to receive a first reactant/product mixture from the sono-reactor section and is configured mix the first reactant/product mixture therein for reaction between unreacted reactants

Methodology Applied
Scientific EffectPassive mixing:

Implementation Method 3

a product separation section that is configured to receive a second reactant/product mixture from the static mixer section and is configured to separate a product from the second reactant/product mixture

Methodology Applied
Scientific EffectPhase separation:

Data Source

PatentUS10786801B2Continuous sono-chemical reactors and methods of using the same
Publication Date: 2020.09.29 KHALIFA UNIV OF SCI & TECH
  • US10786801B2 patent drawing
  • US10786801B2 patent drawing
  • US10786801B2 patent drawing

AI summary

Sono-chemical reactors and methods of using the same are provided. The sono-chemical reactors may include a plurality of sections that are sequentially connected along a longitudinal direction of the sono-chemical reactor. The plurality of sections may include a sono-reactor section that includes a reactant inlet through which reactants are supplied into the sono-reactor section and a static mixer section that is configured to receive a first reactant/product mixture from the sono-reactor section and is configured mix the first reactant/product mixture therein for reaction between unreacted reactants. An inner space of the sono-reactor section may taper along the longitudinal direction of the chemical reactor away from the reactant inlet. The plurality of sections may also include a product separation section that is configured to receive a second reactant/product mixture from the static mixer section and is configured to separate a product from the second reactant/product mixture.