Spark Plug Insulator Grain Boundary Phase Composition

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Solution Overview

Problem

Spark plug insulators face challenges in maintaining dielectric strength and mechanical strength due to surface discharge channeling, which can lead to a decline in performance under high temperatures and mechanical stress.

Innovation Solution

An insulator for spark plugs with a grain boundary phase containing specific elements like magnesium, calcium, strontium, lanthanum, and zirconium, titanium, and niobium, optimized in composition and area ratio to enhance dielectric strength and reduce channeling, is developed. This composition forms a high-melting-point glass phase and provides conductive properties to manage energy distribution during discharge.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the insulator is formed with alumina-based sintered body to obtain excellent thermal resistance and dielectric strength, then dielectric strength is improved, but surface discharge channeling occurs leading to performance decline under high temperatures

Engineering Contradiction:
Improvedielectric strengthVSAvoidsurface discharge channeling
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the grain boundary phase by incorporating specific elements (group 13: Ga, In, Tl; group 14: Ge, Sn, Pb; group 15: Sb, Bi) in controlled amounts. This compositional modification alters the physical and chemical properties of the grain boundary phase, enabling it to resist surface discharge channeling while maintaining dielectric strength under high temperature conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite grain boundary phase by combining multiple elements (group 2A, rare earth, and first element group elements) with alumina particles. This composite structure leverages the synergistic effects of different elements to achieve both high dielectric strength and resistance to surface discharge channeling, resolving the contradiction between these two properties.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If sintering additives like silicon oxide, calcium oxide, or magnesium oxide are employed to achieve reduction in sintering temperature and improvement of sinterability, then sinterability is improved, but dielectric strength characteristics may decline under high temperatures

Engineering Contradiction:
ImprovesinterabilityVSAvoiddielectric strength characteristics under high temperatures
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent modifies the sintering additive composition by introducing specific elements (group 13: Ga, In, Tl; group 14: Ge, Sn, Pb; group 15: Sb, Bi) into the grain boundary phase. This changes the thermal and electrical properties of the sintered body, allowing maintenance of dielectric strength characteristics even at high temperatures while preserving improved sinterability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops a composite grain boundary phase containing group 2A elements, rare earth elements, first element group elements, and silicon, which forms a complex composite material structure. This composite grain boundary phase simultaneously provides good sinterability (through the original sintering additives) and high-temperature dielectric strength (through the additional elements), resolving the contradiction between ease of manufacture and reliability.

Inventive Principle:
Principle #40Composite materials

3Reliability

If a rare earth element is contained in the insulator to heighten the melting point of grain boundary phase, then dielectric strength under high temperatures is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvedielectric strength under high temperaturesVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent optimizes the concentration parameters of rare earth elements and other elements in the grain boundary phase. By controlling the amounts of each element within specific ranges, the patent achieves high-temperature dielectric strength while managing manufacturing complexity through standardized compositional specifications.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a multi-element composite grain boundary phase that integrates rare earth elements with group 2A elements, first element group elements, and silicon. This composite approach distributes the functional requirements across multiple elements, where each contributes specific properties, thereby achieving high-temperature reliability while maintaining manageable manufacturing processes through established ceramic fabrication techniques.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces channeling, maintains excellent dielectric strength characteristics, and prevents mechanical weakness, ensuring stable performance even under high temperatures and mechanical stress.

Implementation Method 1

This ensures reducing softening of the grain boundary phase when the insulator becomes a high temperature

Methodology Applied
Scientific EffectHigh-melting-point glass phase formation: Vitrification

Implementation Method 2

to obtain excellent thermal resistance, dielectric strength characteristics and mechanical strength

Methodology Applied
Scientific EffectDielectric strength: Dielectric

Data Source

PatentUS9160145B2Insulator for spark plug and spark plug
Publication Date: 2015.10.13 NITERRA CO LTD
  • US9160145B2 patent drawing
  • US9160145B2 patent drawing
  • US9160145B2 patent drawing

AI summary

An insulator for spark plug with a main constituent of alumina and containing silicon includes a grain boundary phase positioned between alumina particles. The grain boundary phase contains: a group 2A element; a rare earth element; and at least one kind of zirconium, titanium, chrome, niobium, manganese, and iron (a first element). Assuming that a total amount of the rare earth element is X (mass %), a total amount of the group 2A element is Y (mass %), and a total amount of the first element is Z (mass %), the following are met:0.40≦Y/X≦2.000.10≦Z/X≦0.40.