Downhole Spectrometer Interfacial Tension Prediction

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Solution Overview

Problem

Current methods for estimating residual oil saturation and recoverable oil in hydrocarbon reservoirs are limited by the lack of accurate measurements of interfacial tension (IFT) and reservoir rock wettability, which are influenced by surface active constituents and vary with temperature, pressure, and fluid composition.

Innovation Solution

A downhole tool equipped with a spectrometer and processor to measure the concentration of surface active species, calculating IFT by correlating acid-base IFT with hydrocarbon IFT using formulas like γ=γHC+γAB, where γAB is the acid-base IFT contribution and γHC is the hydrocarbon fluid IFT contribution, allowing for real-time IFT determination in complex fluid systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional methods are used to estimate residual oil saturation and recoverable oil, then the estimation process is simple, but the accuracy of IFT and wettability measurements is insufficient

Engineering Contradiction:
ImproveIFT measurement accuracyVSAvoiddownhole tool complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces conventional mechanical IFT measurement methods with spectroscopic analysis. The downhole tool uses a spectrometer to measure the concentration of surface active species, which then calculates IFT using the formula γ=γHC+γAB. This substitution of optical/spectroscopic methods for mechanical measurement systems enables accurate IFT determination without the complexity of traditional mechanical interfacial tension devices.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces surface active species concentration as an intermediary parameter to determine IFT. Instead of measuring IFT directly, the spectrometer measures the concentration of surface active constituents, which then serves as the basis for calculating IFT through established relationships. This intermediary measurement approach simplifies the direct measurement challenge while maintaining accuracy.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If direct measurement of surface active species is implemented, then IFT prediction accuracy is improved, but the device complexity and measurement system complexity increase

Engineering Contradiction:
ImproveIFT prediction reliabilityVSAvoidspectrometer and processing system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical IFT measurement systems with spectroscopic detection. The spectrometer uses optical methods to detect surface active species concentration, which is then processed through computational algorithms to predict IFT. This substitution provides reliable IFT predictions under reservoir conditions while avoiding the mechanical complexity of traditional IFT measurement devices.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the measurement parameter from direct IFT measurement to surface active species concentration measurement. By measuring concentration of surface active constituents and using the relationship γAB=f(C), the system achieves reliable IFT prediction through parameter transformation, which is more suitable for downhole spectroscopic measurement capabilities.

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If IFT measurements are taken under reservoir conditions, then the measurements reflect actual downhole conditions, but the measurement difficulty and technical challenge increase

Engineering Contradiction:
Improvedownhole IFT measurement accuracyVSAvoiddownhole measurement difficulty
Core Design Contradiction:
Measurement precisionVSDifficulty of detecting and measuring

Solution Approach 1:

The patent replaces difficult mechanical IFT measurement procedures with spectroscopic detection that is better suited for downhole conditions. The spectrometer can operate under high temperature and pressure reservoir conditions to measure surface active species concentration, which is then used to calculate IFT. This substitution overcomes the technical challenges of direct mechanical measurement in harsh downhole environments.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses surface active species concentration as an intermediary that can be measured spectroscopically under reservoir conditions. This intermediary parameter serves as a proxy for IFT, allowing indirect measurement that is feasible under downhole conditions where direct IFT measurement would be extremely difficult or impossible.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate prediction and measurement of IFT downhole, improving the estimation of residual oil saturation and recoverable oil by directly measuring surface active species and their impact on interfacial tension, even at high pressures and temperatures.

Implementation Method 1

a downhole fluid analysis module including a spectrometer capable of measuring a concentration of a surface active species in the fluid

Methodology Applied
Scientific EffectAbsorption Spectroscopy: Absorption Spectroscopy

Data Source

PatentUS11761873B2Method to predict downhole reservoir fluids interfacial tension
Publication Date: 2023.09.19 SCHLUMBERGER TECH CORP
  • US11761873B2 patent drawing
  • US11761873B2 patent drawing
  • US11761873B2 patent drawing

AI summary

Methods may include emplacing a downhole tool within a wellbore, sampling a fluid downhole with the downhole tool; analyzing the fluid, and calculating an interfacial tension (IFT), wherein calculating the acid-base IFT contribution comprises measuring a concentration of a surface-active species directly. Apparatuses for measuring an interfacial tension (IFT) in a fluid downhole may be part of a downhole tool and may include a sampling head to sample the fluid; and a downhole fluid analysis module that includes a spectrometer capable of measuring a concentration of a surface-active species in the fluid, and a processor configured to determine the IFT of the fluid downhole based on the measured concentration of the surface-active species.