Spectrophotometer A/D Conversion Time Controller for Wavelength Validation

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Solution Overview

Problem

The fluctuation in emission intensity of AC-energized light sources, such as the low-pressure mercury lamp, due to AC power frequency affects the accuracy of wavelength correctness validation in spectrophotometers, particularly in high-accuracy applications where slight discrepancies can cause significant issues.

Innovation Solution

A spectrophotometer with an A/D conversion time controller that adjusts the A/D conversion time to be equal to or longer than five times the cycle of the commercial power supply during wavelength correctness validation, and includes a determiner to assess and adjust for periodic fluctuations in emission intensity, ensuring accurate validation even with AC-energized light sources.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a low-pressure mercury lamp is used for wavelength correctness validation, then validation can be performed in the ultraviolet region, but the emission intensity fluctuates due to AC power frequency

Engineering Contradiction:
Improvewavelength correctness validation accuracyVSAvoidemission intensity stability
Core Design Contradiction:
Measurement precisionVSStability of the object's composition

Solution Approach 1:

The patent applies periodic action by synchronizing the A/D conversion timing with the AC power frequency cycle. The A/D converter is controlled to perform conversions at specific phases within each power cycle, ensuring that measurements are taken at consistent points in the emission intensity waveform. This transforms the unstable periodic fluctuation into a controlled sampling strategy that eliminates measurement errors.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent changes the timing parameter of the A/D conversion process to match the AC power frequency. By adjusting the conversion timing to occur at specific phases (e.g., peak or zero-crossing points) of the power cycle, the system captures stable emission intensity values. This parameter adjustment transforms the measurement process to be synchronous with the light source's operational cycle.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If the sampling period is shortened for more precise digital conversion, then conversion precision improves, but data size increases

Engineering Contradiction:
Improvedigital conversion precisionVSAvoiddata size
Core Design Contradiction:
Measurement precisionVSQuantity of substance

Solution Approach 1:

The patent maintains continuous useful action by performing A/D conversion at every appropriate phase of the AC power cycle rather than skipping measurements. Although the sampling rate is effectively reduced compared to continuous high-rate sampling, each measurement point captures critical information about the emission intensity at that phase, maintaining measurement completeness while reducing data volume.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent applies partial action by selecting only the essential sampling points within each AC power cycle that provide sufficient information for wavelength correctness validation. Instead of continuously sampling at maximum rate, the system samples at specific critical phases (such as peak intensity or zero-crossing points), obtaining adequate measurement data with reduced sampling frequency and consequently smaller data size.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach stabilizes the emission intensity measurement, reducing wavelength errors and ensuring accurate validation of wavelength correctness, particularly for AC-energized light sources, thereby supporting higher accuracy in spectrophotometric measurements.

Implementation Method 1

detecting the light after the interaction (e.g. transmitted, reflected, scattered or fluorescent light) with a photodetector

Methodology Applied
Scientific EffectPhotoelectric Effect: Photoelectric Effect

Implementation Method 2

monochromatic light having a specific wavelength is extracted by introducing light emitted from a light source into a light separator

Methodology Applied
Scientific EffectDiffraction: Diffraction

Data Source

PatentUS9784616B2Spectrophotometer
Publication Date: 2017.10.10 SHIMADZU CORP
  • US9784616B2 patent drawing
  • US9784616B2 patent drawing
  • US9784616B2 patent drawing

AI summary

Provided is a spectrophotometer having a sample container 30, a light-source unit 10 for casting measurement light into the sample container 30, a photodetector 40 for detecting light obtained from the sample container 30 illuminated with the measurement light, a light separator 20 placed between the light-source unit 10 and the sample container 30, an A/D converter 50 for converting detection signals from the photodetector 40 into digital signals, and an A/D conversion time controller 65 for controlling an A/D conversion time in the A/D converter 50. The A/D converter 50 receives, for each A/D conversion time, detection signals sequentially produced by the photodetector 40, and sequentially outputs values corresponding to the amounts of signals received. The A/D conversion time controller 65 controls the A/D conversion time at five times (preferably, ten times) the cycle of commercial power supplies or longer during wavelength-correctness validation of the light separator 20.