Spent Chromia/Alumina Catalyst as Cement Raw Material

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Solution Overview

Problem

The disposal of spent hydrocarbon dehydrogenation catalysts, which often contain toxic components, poses environmental and health risks due to landfilling, requiring costly long-term maintenance and inefficient land use.

Innovation Solution

Processing spent hydrocarbon dehydrogenation catalysts to produce cement, utilizing them as a raw material and incorporating reducing agents to reduce toxic metal ions, thereby eliminating the need for landfill disposal and meeting environmental standards.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If spent catalysts are disposed via landfilling, then the disposal process is simple, but it causes environmental pollution, requires long-term maintenance, and wastes land resources

Engineering Contradiction:
Improvedisposal process simplicityVSAvoidenvironmental pollution
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful spent catalyst waste into a beneficial raw material for cement production. The spent catalyst, which would otherwise be disposed of in landfills, is processed and used as a substitute for traditional cement raw materials like clay and shale, thereby eliminating environmental pollution while maintaining disposal simplicity through a standardized processing flow

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Ease of manufacture

If spent catalysts are disposed via landfilling, then the disposal method is straightforward, but it incurs high long-term maintenance and surveillance costs

Engineering Contradiction:
Improvedisposal method simplicityVSAvoidlong-term maintenance duration
Core Design Contradiction:
Ease of manufactureVSLoss of time

Solution Approach 1:

The patent implements a recovery approach where spent catalysts are collected, processed through calcination and grinding, and recovered as valuable raw materials for cement production. This eliminates the need for long-term landfill maintenance while maintaining operational simplicity through established cement industry infrastructure

Inventive Principle:
Principle #34Discarding and recovering

3Device complexity

If spent catalysts are disposed via landfilling, then the disposal process requires minimal processing, but it results in inefficient land use

Engineering Contradiction:
Improveprocessing complexityVSAvoidland usage
Core Design Contradiction:
Device complexityVSArea of stationary object

Solution Approach 1:

The patent makes the spent catalyst serve multiple functions: it acts as both a waste disposal solution and a valuable raw material source for cement production. The processed catalyst can replace traditional raw materials in cement manufacturing, thereby reducing landfill land requirements while maintaining minimal processing complexity through integration with existing cement production facilities

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Ease of manufacture

If spent catalysts containing toxic components are disposed via landfilling, then the disposal is straightforward, but it poses significant environmental and health risks

Engineering Contradiction:
Improvedisposal straightforwardnessVSAvoidtoxic component release
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent converts toxic spent catalyst waste into a beneficial cement raw material through a processing sequence including calcination at high temperatures and grinding. The calcination process stabilizes toxic components, and the final cement product meets environmental standards, thereby eliminating toxic release risks while maintaining disposal straightforwardness through integrated processing

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent applies parameter changes by subjecting spent catalysts to high-temperature calcination (typically 800-1200°C) and controlled grinding processes. These parameter changes transform the physical and chemical properties of the catalyst, stabilizing toxic components and creating a safe, environmentally compliant cement raw material that eliminates harmful factor release

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reuses spent catalysts, reducing land usage and environmental impact, while producing cement that meets health and environmental requirements, eliminating the need for long-term maintenance and surveillance of landfill sites.

Implementation Method 1

the disclosed method can use a reducing agent to reduce toxic metal ions such as Cr6+

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 2

processing a spent hydrocarbon dehydrogenation catalyst comprising alumina to produce a processed raw material

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS20240182364A1Utilization of spent chromia/alumina catalyst for cement production
Publication Date: 2024.06.06 SABIC GLOBAL TECHNOLOGIES BV
  • US20240182364A1 patent drawing

AI summary

Methods of producing cement using a spent hydrocarbon dehydrogenation catalyst are disclosed. A spent hydrocarbon dehydrogenation catalyst comprising alumina is processed to produce a processed raw material. The processed raw material is then used as a component for producing the cement. Compositions of cement including the processed raw material are disclosed.