Spherical Polymer Particles via Extrusion Microgranulation

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Solution Overview

Problem

Current methods for producing thermoplastic polymer particles with sizes suitable for powder-based additive manufacturing, such as selective laser sintering, often result in irregularly shaped particles that do not meet the required size and spherical criteria, limiting their effectiveness in these processes.

Innovation Solution

A continuous extrusion process followed by a microgranulation process using a perforated plate with controlled temperature and vibration to produce spherical polymer particles with uniform sizes between 2 μm and 200 μm, ensuring the longest and shortest dimensions differ by no more than a factor of 2.5, and incorporating a cutter head for precise cutting of melt strands into microgranules.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If conventional methods (bead polymerization, emulsified milling, precipitation, grinding) are used to produce small polymer particles, then particle size requirements are met, but particle shape becomes irregular and spherical morphology is not achieved

Engineering Contradiction:
Improvespherical morphologyVSAvoidparticle size uniformity
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The invention changes the physical-chemical parameters of the polymer melt by controlling temperature (maintaining above melting point through heated plates and insulation) and applying vibration (10-1000 Hz), which modifies the melt's flow and solidification behavior to produce spherical particles with uniform size distribution

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Vibration is applied to the polymer melt at frequencies between 10-1000 Hz during extrusion through the perforated plate. This vibration prevents premature solidification, ensures uniform melt flow through all holes, and contributes to forming spherical particles with consistent dimensions

Inventive Principle:
Principle #18Mechanical vibration

2Ease of manufacture

If plastic granules with diameter of 1 mm to 10 mm are used directly, then material is readily available, but particle size is too large for powder-based additive manufacturing processes

Engineering Contradiction:
Improvematerial availabilityVSAvoidparticle size
Core Design Contradiction:
Ease of manufactureVSLength of moving object

Solution Approach 1:

The continuous polymer melt stream is segmented into multiple individual strands as it passes through the perforated plate with multiple holes. Each hole produces a separate melt strand that is then cut into uniform microgranules, achieving particle sizes of 10 μm to 500 μm suitable for additive manufacturing

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A perforated plate with precisely dimensioned holes serves as an intermediary device between the extrusion system and the final powder product. The plate geometry (hole diameter, spacing, arrangement) controls the segmentation and initial shaping of the melt into uniform strands that solidify into spherical particles

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If a continuous extrusion process with perforated plate is used, then production efficiency is improved, but achieving spherical shape with uniform size becomes difficult without additional controls

Engineering Contradiction:
Improvecontinuous productionVSAvoidspherical uniformity
Core Design Contradiction:
ProductivityVSShape

Solution Approach 1:

The system transitions from static extrusion to dynamic extrusion with vibration applied at 10-1000 Hz. This dynamic approach allows continuous production while maintaining spherical particle morphology and uniform size by preventing premature solidification and ensuring consistent melt flow through the perforated plate throughout the continuous process

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively produces spherical polymer particles that are uniformly sized and shaped, enhancing their suitability for powder-based additive manufacturing processes by ensuring consistent particle size and spherical morphology, which improves the cohesion and accuracy of 3D printing outcomes.

Implementation Method 1

maintaining a temperature of the running plate above a melting point of the thermoplastic polymer(s) so that the thermoplastic polymer(s) do not solidify on the running plate

Methodology Applied
Scientific EffectThermal energy maintenance: Heating

Implementation Method 2

A continuous extrusion process followed by a microgranulation process using a perforated plate with controlled temperature and vibration to produce spherical polymer particles

Methodology Applied
Scientific EffectPhase change control: Phase Change

Implementation Method 3

A continuous extrusion process followed by a microgranulation process using a perforated plate with controlled temperature and vibration

Methodology Applied
Scientific EffectMechanical vibration: Vibration

Data Source

PatentEP3549738B1Method for manufacturing ball-shaped polymer particles, and related use
Publication Date: 2022.05.04 LEAN PLASTICS TECH GMBH
  • EP3549738B1 patent drawingFigure 1
  • EP3549738B1 patent drawingFigure 2

AI summary

Method and associated apparatus for producing spherical polymer particles suitable as plastic powder for powder-based additive manufacturing processes, wherein the method according to the invention for producing spherical polymer particles with a particle size of 2 µm to 200 µm from thermoplastic polymers comprises a continuous extrusion process and a subsequent microgranulation process, wherein the microgranulation process is carried out with a mean exit velocity at the hole of 0.00000330 m/s to 3 m/s and a cutting frequency at the hole exit of 0.1 kHz to 16 kHz.