Spherical Titanium Powder Processing for Submicron Particle Control

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Solution Overview

Problem

Existing methods for preparing titanium or titanium alloy powder through centrifugal atomization face challenges such as low yield of submicron-sized fine powder, oxidation, contamination, and inefficiencies in particle size control, leading to high costs and material waste.

Innovation Solution

A method involving hydrogenation, coarse and fine grinding, granulation with a binder, and post-treatment processes to produce spherical titanium or titanium alloy powder, utilizing a sand mill and two-fluid atomization to achieve uniform particle sizes and high purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If centrifugal atomization is used to prepare titanium powder, then the powder can be produced efficiently, but the yield of submicron-sized fine powder is low and particle size control is poor

Engineering Contradiction:
Improvepowder production efficiencyVSAvoidparticle size control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention divides the atomization process into multiple stages with different nozzle configurations. The first nozzle group creates initial droplets while the second nozzle group further atomizes them into finer particles, enabling better particle size control and higher yield of submicron powder while maintaining production efficiency

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses variable parameters during the atomization process, including adjustable nitrogen flow rates, plasma power, and rod rotation speed. This dynamic control allows optimization of particle size distribution to increase submicron powder yield while maintaining efficient production

Inventive Principle:
Principle #15Dynamics

2Productivity

If centrifugal atomization is used, then powder production is efficient, but oxidation and contamination of titanium droplets occur

Engineering Contradiction:
Improvepowder production efficiencyVSAvoidoxidation and contamination
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The invention introduces nitrogen gas as a protective atmosphere during the entire atomization and cooling process. The nitrogen flow from nozzles and the inert environment prevent oxygen contact with molten titanium droplets, eliminating oxidation while maintaining efficient production

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The invention uses nitrogen gas as an intermediary medium that separates the molten titanium droplets from the oxidizing atmosphere. The nitrogen protective layer prevents direct contact between titanium and oxygen, eliminating contamination while preserving production efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If high-speed rotation is used to atomize droplets, then powder production increases, but motor speed decreases due to sealing problems

Engineering Contradiction:
Improvepowder productionVSAvoidmotor speed stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention replaces the mechanical centrifugal atomization method with a plasma-based atomization system. This substitution eliminates the high-speed rotation requirement and associated sealing problems, allowing stable operation while maintaining high powder production efficiency

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the fundamental atomization mechanism from mechanical centrifugal force to plasma thermal arc and gas flow. This parameter change eliminates the need for high-speed rotation, resolving the motor speed stability issue while preserving productive output

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If fixed-length electrode rod is used, then atomization can be performed, but continuous atomization cannot be guaranteed and efficiency is low

Engineering Contradiction:
Improveatomization process simplicityVSAvoidatomization efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The invention implements continuous feeding of titanium material into the plasma arc zone, ensuring uninterrupted atomization. The continuous supply of material and sustained plasma energy input maintain constant production efficiency without the limitations of fixed-length rods

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method significantly improves the yield and quality of submicron-sized powder, enhancing fluidity and molding accuracy for applications like 3D printing and MIM, while reducing environmental impact and production costs.

Implementation Method 1

step S1. hydrogenation: hydrogenating metal titanium or a titanium alloy to form a hydride

Methodology Applied
Scientific EffectHydrogenation: Hydrogenation

Implementation Method 2

melted under the action of a plasma thermal arc

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 3

melted under the action of a plasma thermal arc

Methodology Applied
Scientific EffectElectromagnetic induction heating: Electromagnetic Induction

Implementation Method 4

Molten metal droplets diverge into small droplets in a tangential direction under the action of centrifugal force

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Data Source

PatentUS20250249502A1Method for forming spherical titanium or titanium alloy and application thereof
Publication Date: 2025.08.07 SHANGHAI TIGUAN NEW MATERIAL TECHNOLOGY CO LTD

AI summary

The present application relates to the technical field of preparation of titanium and titanium alloy powder and, in particular, to a method for forming a spherical titanium or titanium alloy with a small particle size and an application thereof. The method for forming a spherical titanium or titanium alloy with a small particle size includes the preparation steps of hydrogenation, coarse grinding, fine grinding, granulation, and aftertreatment. The application of the method for forming a spherical titanium or titanium alloy with a small particle size includes: applying the spherical titanium or titanium alloy with a small particle size produced by the method to a 3D printing powder base material or MIM.