Spin Coating Method for Flat Insulation Films on Fine Particle Substrates

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Solution Overview

Problem

Conventional spin coating methods, such as CVD, struggle to achieve film flatness on substrates with steps due to incomplete penetration of polymer solutions into fine particle films, especially when the films are thick, leading to uneven film deposition.

Innovation Solution

A spin coating method involving a two-stage rotational process where a polymer solution is initially spun onto a fine particle film at high speed, then slowed to allow penetration and evaporation, followed by a third stage of increased rotation to remove excess solution, ensuring thorough penetration and uniform film thickness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a polymer solution is applied onto a thick fine particle film and heat treatment is performed, then the fine particle film can be hardened, but the polymer solution cannot penetrate the fine particle film to the bottom or penetrates only locally

Engineering Contradiction:
Improvefilm flatnessVSAvoidpenetration completeness
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies dynamic control of substrate rotation speed during spin coating. The rotation speed is adjusted in multiple stages: initially at a first rotation speed to spread the polymer solution, then at a slower second rotation speed to allow penetration into the fine particle film, and finally at a third rotation speed to remove excess solution. This dynamic adjustment ensures complete penetration and uniform film formation without sacrificing flatness.

Inventive Principle:
Principle #15Dynamics

2Volume of moving object

If the fine particle film is formed to be thick to improve insulation performance, then the film thickness increases, but the polymer solution penetration becomes incomplete

Engineering Contradiction:
Improvefilm thicknessVSAvoidfilm uniformity
Core Design Contradiction:
Volume of moving objectVSManufacturing precision

Solution Approach 1:

The patent employs periodic action through multi-stage spin coating with different rotation speeds. The process cycles through spreading the polymer solution, allowing penetration at reduced speed, and removing excess material. This periodic variation in rotation speed enables complete penetration even through thick fine particle films, ensuring uniform film formation and consistent insulation performance.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method ensures complete penetration of the polymer solution into the fine particle film, resulting in a thick, flat, and high-quality insulation film, even in complex trench structures, while allowing for adjustable film thickness and improved surface flatness.

Implementation Method 1

When the fine particle film is formed to be thick, the polymer solution may be hardened, while the polymer solution has not penetrated the fine particle film to the bottom of the fine particle film

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

applying a polymer solution onto the fine particle film, and hardening the fine particle film and the polymer solution by heat treatment

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

Rotating of the underlying material is stopped or a rotational speed of the underlying material is reduced to 10 rpm or less. The underlying material is rotated after a first period elapses after the stopping of the rotating of the underlying material, or the rotational speed of the underlying material is increased after the first period elapses after the reducing of the rotational speed of the underlying material to spin off the solution from the upper surface of the first material film

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Data Source

PatentUS9793111B2Spin coating method and manufacturing method of electronic component
Publication Date: 2017.10.17 KIOXIA CORP
  • US9793111B2 patent drawing
  • US9793111B2 patent drawing
  • US9793111B2 patent drawing

AI summary

A spin coating method according to an embodiment includes forming a first material film on an underlying material. The underlying material is rotated while a solution of a second material film is supplied onto an upper surface of the first material film to make the solution stay on the upper surface of the first material film. Rotating of the underlying material is stopped or a rotational speed of the underlying material is reduced to 10 rpm or less. The underlying material is rotated after a first period elapses after the stopping of the rotating of the underlying material, or the rotational speed of the underlying material is increased after the first period elapses after the reducing of the rotational speed of the underlying material to spin off the solution from the upper surface of the first material film.