Spin Defect Centers for Room-Temperature Nuclear Spin Polarization

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional magnetic resonance techniques face limitations in achieving high spin polarization at room temperature, requiring expensive and bulky magnets, and existing dynamic polarization methods are either temperature-limited or inefficient.

Innovation Solution

A method involving a substrate with spin defect centers, such as nitrogen-vacancy centers in diamond, exposed to a magnetic field and illumination to induce polarized spins in an analyte, achieving higher spin polarization at room temperature.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional magnets are used to induce spin polarization, then spin alignment increases, but device size and cost increase significantly

Engineering Contradiction:
Improvespin polarizationVSAvoidmagnet size and cost
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent introduces a photosensitive material layer as an intermediary between the light source and the analyte. This layer absorbs photons and generates polarized spins that then interact with the analyte, mediating the energy transfer and enabling polarization without requiring strong magnetic fields

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the mechanical/electromagnetic system (bulky magnets) with an optical system (light source and photosensitive material). The optical pumping mechanism substitutes for the traditional magnetic field-based polarization method, achieving the same effect with much smaller and cheaper components

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If dynamic polarization methods are used to achieve higher spin polarization, then polarization increases, but temperature requirements become extremely low

Engineering Contradiction:
Improvespin polarizationVSAvoidoperating temperature
Core Design Contradiction:
Measurement precisionVSTemperature

Solution Approach 1:

The patent changes the fundamental parameter of how polarization is achieved - instead of relying on thermal effects that require low temperatures, it uses optical pumping parameters that work effectively at room temperature. The photosensitive material's electronic transitions enable polarization without thermal constraints

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If complex hyperpolarization instruments are used, then spin polarization improves, but device complexity and cost increase

Engineering Contradiction:
Improvespin polarizationVSAvoidinstrument complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent extracts only the essential polarization-generating component (photosensitive material layer) from complex hyperpolarization instruments. By isolating and utilizing just this functional element, the system achieves polarization without the bulky and expensive additional components of traditional hyperpolarization devices

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent applies the photosensitive material locally as a thin layer (1-100 nm) on a substrate, concentrating the polarization function in a specific location rather than requiring a complex instrument. This localized approach simplifies the overall system while maintaining effective polarization

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables a significant increase in spin polarization, enhancing the sensitivity of magnetic resonance measurements and allowing for portable, cost-effective applications in diagnostics and analysis.

Implementation Method 1

The spin defect centers are exposed to a magnetic field and illumination to produce polarized spins

Methodology Applied
Scientific EffectOptical pumping:

Implementation Method 2

The spin defect centers are exposed to a magnetic field and illumination to produce polarized spins

Methodology Applied
Scientific EffectMagnetic field alignment: Magnetic Field

Implementation Method 3

The polarized spins in the spin defect centers then induce spin polarization in the analyte

Methodology Applied
Scientific EffectSpin polarization induction: Magnetism

Data Source

PatentUS10330750B2Method and apparatus for polarizing nuclear and electronic spins
Publication Date: 2019.06.25 RES FOUND THE CITY UNIV OF NEW YORK
  • US10330750B2 patent drawing
  • US10330750B2 patent drawing
  • US10330750B2 patent drawing

AI summary

A method and apparatus for polarizing nuclear or electronic spins is disclosed. An analyte is passed near a surface that has a plurality of spin defect centers implanted within 10 nm of the surface. The spin defect centers are exposed to a magnetic field and illumination to produce polarized spins. The polarized spins then induce spin polarization in the analyte.