Spin-On SiC Cap Layers for Defect-Reduced Self-Aligned Contacts

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Solution Overview

Problem

Conventional self-aligned contact processes using CVD silicon carbide (SiC) for trench contacts face issues with void formation and planarization defects, which are not adequately addressed by existing methods.

Innovation Solution

The use of spin-on silicon carbide (SiC) as a cap layer material for conductors, allowing for improved etch selectivity and reduced defectivity by forming self-aligned contacts through specific etch processes and planarization techniques, replacing traditional deposition methods like CVD or PVD.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If CVD silicon carbide is used as cap material for trench contacts, then etch selectivity is achieved, but void formation and planarization defects occur

Engineering Contradiction:
Improveetch selectivityVSAvoiddefectivity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the deposition method parameter from CVD to spin-on coating, which fundamentally alters how the silicon carbide cap layer is formed. This parameter change eliminates the inherent void formation and planarization defects associated with CVD while maintaining the material's etch selectivity properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses spin-on silicon carbide as a cap material that copies the functional properties of CVD silicon carbide (etch selectivity) without replicating its manufacturing defects. The spin-on process creates a defect-free layer that serves the same protective and selective etching functions

Inventive Principle:
Principle #26Copying

2Productivity

If device linewidths are shrunk to meet design criteria, then device density increases, but etch selectivity requirements become more demanding

Engineering Contradiction:
Improvedevice densityVSAvoidetch selectivity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

By changing the cap material deposition method to spin-on, the patent achieves superior surface uniformity and thickness control, which provides more consistent etch selectivity ratios. This enhanced parameter control is critical for maintaining reliable self-aligned contact formation as device dimensions shrink

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If CVD SiC is deposited and planarized, then cap layers are formed for trench contacts, but defectivity increases and yield decreases

Engineering Contradiction:
Improvecap layer formationVSAvoidyield
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent replaces the mechanical planarization process (CMP) with a spin-on deposition process that inherently produces planar surfaces. This substitution eliminates the need for subsequent planarization steps that cause defects and yield loss, while still achieving the required cap layer formation

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The spin-on process copies the functional outcome of CVD deposition and planarization without replicating the defect formation mechanisms, thereby achieving cap layer formation with significantly improved yield

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the yield and reduces defects in self-aligned contact formation, providing better etch selectivity and planarization results compared to traditional methods, thus meeting the demands of shrinking device criteria.

Implementation Method 1

forming a second cap layer over the plurality of second conductors, wherein the second cap layer is formed by spin coating a second dielectric material onto the substrate

Methodology Applied
Scientific EffectSpin coating: Spin Coating

Implementation Method 2

spin coating a second dielectric material onto the substrate

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS12080599B2Methods for forming self-aligned contacts using spin-on silicon carbide
Publication Date: 2024.09.03 TOKYO ELECTRON LTD
  • US12080599B2 patent drawing
  • US12080599B2 patent drawing
  • US12080599B2 patent drawing

AI summary

Methods and improved process flows are provided herein for forming self-aligned contacts using spin-on silicon carbide (SiC). More specifically, the disclosed methods and process flows form self-aligned contacts by using spin-on SiC as a cap layer for at least one other structure, instead of depositing a SiC layer via plasma vapor deposition (PVD), chemical vapor deposition (CVD), atomic layer deposition (ALD), etc. The other structure may be a source and drain contact made through the use of a trench conductor. By utilizing spin-on SiC as a cap layer material, the disclosed methods and process flows avoid problems that typically occur when SiC is deposited, for example by CVD, and subsequently planarized. As such, the disclosed methods and process flows improve upon conventional methods and process flows for forming self-aligned contacts by reducing defectivity and improving yield.