Dry-Jet Wet Spinning Spinneret Dew Condensation Control

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Solution Overview

Problem

High-density spinnerets with numerous holes in dry-jet wet spinning systems face issues with dew condensation, leading to clogging, fiber adhesion, and yarn breaks, especially during high-speed spinning or when the distance between the spinneret and coagulation bath is short, as existing methods are insufficient in preventing vapor accumulation and require costly equipment for humidity control.

Innovation Solution

A method involving a unidirectional air flow in the gas-phase portion between the spinneret and coagulation bath, with a specific air flow rate and low relative standard deviation of wind velocities, effectively suppresses dew condensation by maintaining controlled humidity and air flow, suitable for spinnerets with 2000 to 50,000 holes and a distance of less than 20 mm to the coagulation bath.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high-speed spinning or hole multiplication is carried out to increase productivity, then fiber production efficiency is improved, but dew condensation occurs on the spinneret surface causing clogging and fiber adhesion

Engineering Contradiction:
Improvefiber production efficiencyVSAvoiddew condensation on spinneret
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

A gas-phase portion with controlled air flow is introduced as an intermediary between the spinneret and coagulation bath. This gas phase acts as a mediator that prevents direct contact between solvent vapor and the spinneret surface, thereby preventing dew condensation while allowing high-speed spinning to proceed efficiently

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the parameters of the gas-phase portion by controlling air flow rate (0.0008-0.0020 m³/s) and humidity (10-30% RH) to prevent dew condensation. By adjusting these parameters, the system enables high-speed spinning without the harmful effects of vapor accumulation on the spinneret surface

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the number of holes in the spinneret is increased to enhance productivity, then fiber production rate is improved, but solvent vapor accumulates in the gas-phase portion leading to dew condensation

Engineering Contradiction:
Improvefiber production rateVSAvoidsolvent vapor accumulation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and removes solvent vapor from the gas-phase portion by introducing controlled air flow that carries the vapor away from the spinneret surface. This extraction prevents vapor accumulation and subsequent dew condensation, allowing high-hole-density spinnerets to operate without causing harmful effects

Inventive Principle:
Principle #2Taking out (Extraction)

3Productivity

If the distance between spinneret and coagulation bath is reduced to improve productivity, then fiber formation efficiency is improved, but dew condensation occurs more readily due to shorter gas-phase portion

Engineering Contradiction:
Improvefiber formation efficiencyVSAvoiddew condensation
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

Even with a short gas-phase portion, the controlled air flow acts as an intermediary that prevents solvent vapor from reaching the spinneret surface. This mediator function allows the gas phase to remain effective in preventing dew condensation despite the reduced distance between spinneret and coagulation bath

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces dew condensation on the spinneret, improving fiber production stability and appearance by preventing clogging and yarn breaks, enhancing productivity and maintaining fiber quality, particularly for acrylonitrile precursor fibers used in carbon fiber production.

Implementation Method 1

a gas-phase portion formed in a vertically downward direction from an extrusion surface of the spinneret to a coagulation bath liquid surface has a unidirectional air flow

Methodology Applied
Scientific EffectAir flow: Convection

Implementation Method 2

extruding, from a spinneret, a spinning dope solution containing a fiber-forming polymer dissolved in a solvent, once allowing the solution to run in air, and then guiding the solution into a coagulation bath liquid to allow coagulation

Methodology Applied
Scientific EffectCoagulation: Coagulation

Data Source

PatentEP3604636B1Fiber production method and carbon fiber production method
Publication Date: 2023.10.04 TORAY INDUSTRIES INC
  • EP3604636B1 patent drawingFigure 1
  • EP3604636B1 patent drawing
  • EP3604636B1 patent drawing

AI summary

A method of producing a fiber, the method including extruding, from a spinneret 1, a spinning dope solution containing a fiber-forming polymer dissolved in a solvent, once allowing the solution to run in air, and then guiding the solution into the liquid of a coagulation bath 4 to allow coagulation, wherein a gas-phase portion formed in a vertically downward direction from an extrusion surface of the spinneret 1 to the liquid surface of the coagulation bath 4 has a unidirectional air flow, and has an air flow rate per unit time (Af) which satisfies, in relation to the amount of the solvent in the spinning dope solution per unit time (As) in the gas-phase-portion volume (Vh), the relational expression 0.0008 m3 ≤ Af/(As/Vh) ≤ 0.0015 m3. A method of producing a fiber, which, in dry-jet wet spinning, suppresses occurrence of dew condensation in the spinneret, and reduces deterioration of the appearance caused by winding on rollers in the subsequent process or by fuzzing or yarn break in the stretching process, to enable significant improvement of the productivity and the appearance as a whole, is provided.