Spiro-Anthracene Blue OLED Dopant for High Efficiency

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Solution Overview

Problem

Current blue phosphorescent materials for OLEDs suffer from low luminous efficiency, short lifespan, and poor color purity, limiting their use in full-color display applications.

Innovation Solution

An organic compound with a spiro-anthracene core and aromatic or heteroaromatic substituents is developed, enhancing color purity and luminous efficiency while reducing driving voltage and power consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If blue phosphorescent materials are used in OLEDs, then blue emission is achieved, but luminous efficiency is low and lifespan is short

Engineering Contradiction:
Improveluminous efficiencyVSAvoidlifespan
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the emitting material by introducing a spiro-anthracene core with specific aromatic or heteroaromatic substituents (R1 and R2 groups). This structural parameter change results in improved luminous efficiency and extended lifespan compared to conventional blue phosphorescent materials, while maintaining the required blue emission properties.

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If conventional blue dopant materials are used, then blue emission is achieved, but color purity is low

Engineering Contradiction:
Improvecolor purityVSAvoidluminous efficiency
Core Design Contradiction:
Illumination intensityVSLoss of energy

Solution Approach 1:

The patent applies local quality by introducing specific substituent groups (R1 and R2) at particular positions on the spiro-anthracene core structure. These localized structural modifications optimize the emission characteristics to achieve high color purity while maintaining or improving luminous efficiency, resolving the trade-off between these two parameters.

Inventive Principle:
Principle #3Local quality

3Use of energy by moving object

If multiple-layered emitting layer is used, then luminous efficiency is enhanced, but device complexity increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidemitting layer structure
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The spiro-anthracene core compound with aromatic or heteroaromatic substituents serves multiple functions simultaneously: it acts as both the host material and the emitting dopant, and provides both charge transport and exciton management functions. This multi-functionality allows a simplified single-layer structure to achieve the luminous efficiency that previously required complex multi-layer structures.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic compound improves the luminous efficiency, color purity, and lifespan of OLEDs, enabling their use in full-color displays by acting as a dopant in the emitting material layer, specifically enhancing blue emission.

Implementation Method 1

when electrical charges are injected into an emitting layer between an electron injection electrode (i.e., cathode) and a hole injection electrode (i.e., anode), electrical charges are combined to be paired, and then emit light as the combined electrical charges are disappeared

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11417845B2Organic compound, organic light-emitting diode and organic light-emitting device containing the compound
Publication Date: 2022.08.16 LG DISPLAY CO LTD
  • US11417845B2 patent drawing
  • US11417845B2 patent drawing
  • US11417845B2 patent drawing

AI summary

An organic compound having a spiro-anthracene core and an aromatic or heteroaromatic group and/or an amino group bonded to the core, and an organic light-emitting diode and an organic light-emitting device including the organic compound are disclosed. Since the organic compound of the present disclosure has a rigid structure and a substantially narrow full width at half maximum (FWHM), it is possible to manufacture an organic light-emitting diode and an organic light-emitting device with lowered driving voltages and enhanced luminous efficiency and color purity using the organic compound.