Spray-Dried Powder Manufacturing via Segmented Emulsification

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The existing methods for manufacturing water-dispersible powders with high fat-soluble compound content, such as beta-carotene, face challenges in achieving low filter residue and high compound concentration during the spray-drying process, often resulting in poor quality powders due to particle collapse and agglomeration issues.

Innovation Solution

A process involving a bimodal particle-solvent distribution is achieved by splitting the emulsification and evaporation steps into multiple stages, using a specialized apparatus with multiple mixing and evaporation units, to control the solvent removal and maintain particle stability, thereby producing high-quality, water-dispersible powders with enhanced fat-soluble compound content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If the emulsification and evaporation steps are performed in a single stage, then the process is simple, but the particle distribution becomes unimodal leading to particle collapse and agglomeration

Engineering Contradiction:
Improveprocess complexityVSAvoidparticle size distribution
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The manufacturing process is divided into multiple stages: first emulsification stage forming initial particles, then evaporation stage removing solvent, then second emulsification stage adding more fat-soluble compound, and finally second evaporation stage. This segmentation creates a bimodal particle distribution that prevents collapse and agglomeration, resolving the contradiction between process simplicity and particle quality.

Inventive Principle:
Principle #1Segmentation

2Quantity of substance

If a high content of fat-soluble compound is used in the dispersion, then the powder has high colorant content, but the filter residue increases

Engineering Contradiction:
Improvefat-soluble compound contentVSAvoidfiltration quality
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The first emulsification and evaporation stages are performed before adding the remaining fat-soluble compound. This preliminary action creates a stable particle distribution framework that can accommodate additional compound without causing agglomeration, allowing high final compound content while maintaining low filter residue.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If the solvent is completely removed in one evaporation step, then the process is efficient, but particle stability is compromised leading to collapse

Engineering Contradiction:
Improveevaporation efficiencyVSAvoidparticle stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The evaporation process is segmented into at least two separate evaporation stages interspersed with emulsification stages. This segmentation allows partial solvent removal followed by particle stabilization through additional emulsification, maintaining particle stability while achieving complete solvent removal ultimately, thus resolving the contradiction between evaporation efficiency and particle stability.

Inventive Principle:
Principle #1Segmentation

4Manufacturing precision

If small particle size is achieved for good coloration, then the powder quality is high, but the manufacturing process becomes more difficult

Engineering Contradiction:
Improveparticle sizeVSAvoidprocess difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The process uses periodic alternating action between emulsification and evaporation stages. Each cycle refines the particle size distribution and prevents agglomeration, achieving small uniform particle sizes suitable for high-quality coloration while keeping the process manageable through rhythmic repetition of standardized operations.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces filter residue and allows for the production of powders with higher fat-soluble compound content, ensuring excellent quality and dispersibility, even with low-performing solvents like ethyl acetate or isopropyl acetate, by preventing particle collapse and agglomeration.

Implementation Method 1

The dispersion to be spray-dried is obtained by removing the solvent of an intermediate composition in an evaporator

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

Water-dispersible powders comprising a fat-soluble compound may be manufactured by spray-drying

Methodology Applied
Scientific EffectSpray-drying: Evaporation

Data Source

PatentEP3784055B1Apparatus and process for manufacturing of powders with a fat-soluble component
Publication Date: 2024.05.01 DSM IP ASSETS BV
  • EP3784055B1 patent drawingFigure 1
  • EP3784055B1 patent drawingFigure 2
  • EP3784055B1 patent drawingFigure 3

AI summary

The present invention relates to a method of manufacturing spray-dried powders. During the process, a solvent is used. The process is done in multiple steps such that the emulsification mass ratio is low when removal of the solvent is started. Preferred solvents are isopropyl acetate and ethyl acetate. The invention also relates to a set-up to run the inventive process at industrial scale.