Spring Steel Composition for High-Temperature Nitriding Strength

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Solution Overview

Problem

High-strength spring materials for automobile transmissions face challenges in maintaining fatigue resistance and nitriding properties while avoiding the formation of low-temperature structures and excessive grain growth, which can lead to reduced strength and increased production time.

Innovation Solution

A wire rod and steel wire composition with specific alloying elements (C, Si, Mn, Cr, Mo, V, and Fe) and manufacturing processes that include heating, rolling, and controlled cooling to achieve a microstructure with a high pearlite content, suppressed grain size, and uniform carbide distribution, ensuring improved fatigue resistance and nitriding properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If nitriding is performed at high temperature (500°C or higher) to reduce nitriding time, then productivity is improved, but the strength of spring steel is greatly reduced because tempering heat treatment temperature is 450°C or lower

Engineering Contradiction:
Improvenitriding timeVSAvoidstrength of spring steel
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the steel by adding specific amounts of carbide-forming elements (Cr: 0.9-1.6%, Mo: 0.1-0.25%, V: 0.1-0.25%) to enable nitriding at high temperatures without excessive strength loss. This compositional modification allows the steel to maintain sufficient strength while achieving faster nitriding

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of tempered martensite (5-20%) and pearlite (78-90%), where the tempered martensite provides strength and the pearlite provides ductility and resistance to strength deterioration during high-temperature nitriding

Inventive Principle:
Principle #40Composite materials

2Strength

If large quantities of carbide-forming elements (Cr, Mo, V) are added to prevent strength decrease during nitriding, then strength is maintained, but breakage occurs during wire rod production due to low-temperature structure formation and constant-temperature transformation time is greatly increased

Engineering Contradiction:
Improvestrength during nitridingVSAvoidwire rod production efficiency
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent optimizes the parameters of carbide-forming element content to specific ranges (Cr: 0.9-1.6%, Mo: 0.1-0.25%, V: 0.1-0.25%) that are sufficient to prevent strength loss during nitriding but not excessive to cause low-temperature structure formation. This precise parameter control avoids breakage during wire rod production while maintaining strength

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates local quality differences in the microstructure by controlling the formation of tempered martensite (5-20%) in specific regions, providing localized strength where needed while maintaining overall productivity

Inventive Principle:
Principle #3Local quality

3Weight of moving object

If wire diameter is decreased to achieve weight reduction in high-strength springs, then weight is reduced, but sensitivity to inclusions increases and fatigue limit is lowered

Engineering Contradiction:
Improveweight of springVSAvoidfatigue limit
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters by adding specific amounts of alloying elements (Cr, Mo, V) that enhance the material's resistance to inclusion-induced fatigue, allowing thin-wire springs to maintain high fatigue limits despite reduced diameter

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure with tempered martensite and pearlite that provides enhanced toughness and resistance to inclusion effects, compensating for the reduced wire diameter and maintaining fatigue performance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively enhances the fatigue resistance and nitriding properties of the spring materials, maintaining strength and productivity by preventing low-temperature structure formation and optimizing carbide distribution, thereby improving the overall manufacturing efficiency and performance.

Implementation Method 1

the microstructure comprises 60% or more of a pearlite structure in the C section

Methodology Applied
Scientific EffectPearlite structure formation: Crystallisation

Implementation Method 2

spring manufacturers increase the fatigue limit of spring materials by maintaining strength and improving surface hardness through nitriding

Methodology Applied
Scientific EffectNitriding: Nitriding

Implementation Method 3

heating, rolling, and controlled cooling to achieve a microstructure with a high pearlite content, suppressed grain size, and uniform carbide distribution

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS20240052453A1Wire rod and steel wire for spring, spring with improved fatigue resistance and nitriding properties, and methods for manufacturing same
Publication Date: 2024.02.15 POHANG IRON & STEEL CO LTD

AI summary

Disclosed are a wire rod and a steel wire for a spring, a spring with improved fatigue resistance and nitriding property, and methods for manufacturing same. The wire rod for a spring with improved fatigue resistance and nitriding property according to the present disclosure contains, by wt %, 0.6-0.7% of C, 2.0-2.5% of Si, 0.2-0.5% of Mn, 0.9-1.6% of Cr, 0.015% of less of P, 0.01% of less of S, 0.01% of less of Al, 0.007% of less of N, 0.1-0.25% of Mo, 0.1-0.25% of V, and Fe and inevitable impurities as the balance, wherein Cr+Mn is 1.8% or less, Mo/V is 1.5 or less, and the microstructure includes 60% or more of a pearlite structure in the C section.