Sputtering Target SiO2 Quartz Crystal Structure

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Solution Overview

Problem

Sputtering targets with added SiO2 experience micro cracks and increased particle generation during the sputtering process, leading to longer burn-in times, which hinder the production of high-quality magnetic recording films for hard disk drives.

Innovation Solution

Incorporating quartz as the raw material for SiO2 in the sputtering target, which inhibits the formation of cristobalites, reduces micro cracks, and shortens burn-in time by maintaining target density and preventing particle generation, while allowing for higher SiO2 content per unit volume.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If SiO2 is added to the sputtering target, then magnetic separation of alloy phase is improved, but micro cracks are generated and particle generation increases

Engineering Contradiction:
Improvemagnetic separation qualityVSAvoidparticle generation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the crystal structure parameter of SiO2 from amorphous or cristobalite form to quartz form. This parameter change in the SiO2 crystal structure prevents micro crack formation and particle generation during sputtering, while maintaining the magnetic separation function of SiO2 in the alloy phase.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system where quartz-crystalline SiO2 is combined with ferromagnetic alloy. The specific crystal structure of quartz provides both the magnetic separation function and the structural stability needed to prevent particle generation during sputtering process.

Inventive Principle:
Principle #40Composite materials

2Reliability

If SiO2 is added to the sputtering target, then magnetic separation of alloy phase is improved, but burn-in time is extended

Engineering Contradiction:
Improvemagnetic separation qualityVSAvoidburn-in time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention changes the crystal structure parameter of SiO2 to quartz form, which has different thermal and structural properties compared to amorphous or cristobalite SiO2. This parameter change reduces the burn-in time required during sputtering while maintaining the magnetic separation function.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If conventional SiO2 forms are used, then particle generation occurs, but using quartz prevents particle generation and maintains target density

Engineering Contradiction:
Improveparticle generationVSAvoidSiO2 content per unit volume
Core Design Contradiction:
Object-generated harmful factorsVSQuantity of substance

Solution Approach 1:

The invention changes the crystal structure parameter of SiO2 to quartz form, which has higher density and different packing characteristics. This allows for increased SiO2 content per unit volume in the sputtering target while preventing particle generation during the sputtering process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of quartz in sputtering targets results in reduced particle generation, improved recording density, and cost reduction through shorter burn-in times, enhancing the efficiency and quality of magnetic recording films.

Implementation Method 1

a sputtering target capable of inhibiting the formation of cristobalites that cause the generation of particles during sputtering

Methodology Applied
Scientific EffectCrystallisation: Crystallisation

Implementation Method 2

A magnetic thin film of a magnetic recording medium such as a hard disk is often produced by sputtering a ferromagnetic material sputtering target

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS9605339B2Sputtering target for magnetic recording film and process for production thereof
Publication Date: 2017.03.28 JX NIPPON MINING & METALS CORP
  • US9605339B2 patent drawing
  • US9605339B2 patent drawing

AI summary

A sputtering target for a magnetic recording film containing SiO2, wherein a peak strength ratio of a (011) plane of quartz relative to a background strength (i.e. quartz peak strength/background strength) in an X-ray diffraction is 1.40 or more. An object of this invention is to obtain a sputtering target for a magnetic recording film capable of inhibiting the formation of cristobalites in the target which cause the generation of particles during sputtering, shortening the burn-in time, magnetically and finely separating the single-domain particles after deposition, and improving the recording density.