Stabilized Glow Plasma Control for Accurate Gas Mixture Measurement

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Solution Overview

Problem

Existing glow discharge optical emission spectroscopy (GD-OES) systems face challenges in maintaining stable glow plasmas at atmospheric pressure due to high gas flow rates, high gas concentrations, high voltages, and the high costs and energy intensity of noble carrier gases, leading to plasma quenching and instability, which affects gas analysis accuracy and efficiency.

Innovation Solution

The method involves controlling plasma operating conditions through real-time monitoring and dynamic resonant feedback control of electric fields, adjusting parameters such as electrode geometry, excitation frequency, and impedance to maintain a stable glow discharge within a desired operating range, using a plasma cell with dielectric barriers to shield electrodes and employing inert gases like nitrogen to reduce costs and energy demand.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional DC or RF power sources are used to sustain glow discharge, then the plasma can be maintained, but the discharge becomes inherently unstable and difficult to control

Engineering Contradiction:
Improveglow discharge stabilityVSAvoidcontrol system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The system employs a feedback control mechanism where optical emissions from the plasma are monitored and used to adjust the excitation voltage dynamically. This closed-loop feedback stabilizes the glow discharge by automatically compensating for fluctuations in plasma conditions, eliminating the need for complex external control systems while maintaining reliable operation.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The invention transitions from conventional DC or RF power sources to an alternating excitation voltage operating in a resonant condition. This parameter change in the excitation method fundamentally alters the plasma behavior, enabling stable glow discharge through the resonant interaction between the alternating voltage and plasma particles, thereby improving reliability without increasing device complexity.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If high power is used to sustain the plasma, then the discharge can be maintained, but the stability and control of the glow discharge deteriorates

Engineering Contradiction:
Improveglow discharge stabilityVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The system uses periodic alternating excitation voltage instead of continuous high power input. By applying energy in periodic cycles that resonate with the plasma, the system maintains stable glow discharge with reduced overall energy consumption. The resonant condition ensures efficient energy transfer during each cycle, avoiding the waste associated with continuous high-power application.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The plasma itself provides feedback through its optical emissions, which are monitored to automatically adjust the excitation parameters. This self-regulating mechanism allows the system to maintain stable discharge at optimized power levels without requiring external intervention or excessive energy input, enabling the plasma to self-stabilize at efficient operating conditions.

Inventive Principle:
Principle #25Self-service

3Stability of the object's composition

If dynamic control of electric field is implemented to stabilise glow plasma, then emission stability improves, but the system complexity increases

Engineering Contradiction:
Improveglow discharge emission stabilityVSAvoidfeedback control system complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The system implements feedback control by monitoring optical emissions and using this information to dynamically adjust the alternating excitation voltage. This feedback loop stabilizes the glow discharge emissions by automatically compensating for variations in plasma conditions, achieving high emission stability through an integrated control mechanism that does not significantly increase overall system complexity.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The alternating excitation voltage serves multiple functions simultaneously: it provides the primary energy input to sustain the plasma, creates resonant conditions for stable discharge, and acts as the control parameter that is dynamically adjusted based on feedback. This multi-functionality reduces the need for separate control components, thereby stabilizing emissions without proportionally increasing system complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables stable glow plasmas under varying conditions, allowing for accurate and efficient gas analysis with enhanced signal-to-noise recovery, reducing the need for vacuum systems and minimizing greenhouse gas production.

Implementation Method 1

generating an electric field within a plasma cell using an alternating excitation voltage to excite particles within the cell, to produce a glow discharge from a plasma in the plasma cell in a resonant condition

Methodology Applied
Scientific EffectGlow discharge: Electric Glow Discharge

Implementation Method 2

produce a glow discharge from a plasma in the plasma cell in a resonant condition

Methodology Applied
Scientific EffectResonance: Resonance

Implementation Method 3

monitoring, in each excitation cycle of the alternating excitation voltage, one or more signals that correlate with glow discharge optical emissions from the plasma in the plasma cell

Methodology Applied
Scientific EffectOptical emission: Luminescence

Data Source

PatentEP3719482B1Method of measuring the concentrations of gases in a gas mixture using a stabilised glow plasma
Publication Date: 2026.04.22 SERVOMEX GRP LTD
  • EP3719482B1 patent drawingFigure 1
  • EP3719482B1 patent drawingFigure 2
  • EP3719482B1 patent drawingFigure 3

AI summary

Provided are methods, apparatus and systems for stabilisation of a glow discharge from a plasma. Also provided are methods, apparatus and systems for processing optical signals from a stabilised glow plasma with enhanced signal to noise recovery. A first method comprises: generating an electric field within a plasma cell using an alternating excitation voltage to excite particles within the cell, to produce a glow discharge from a plasma in the plasma cell in a resonant condition; monitoring, in each excitation cycle of the alternating excitation voltage, one or more signals that correlate with glow discharge optical emissions from the plasma in the plasma cell; and, in response to said monitoring, controlling one or more operating conditions for the plasma cell to maintain the glow discharge emissions from the plasma within a desired operating range in each excitation cycle of the alternating excitation voltage. A relatively stable glow discharge optical emission is maintained via dynamic resonant feedback control of operating conditions such as the electric field that is used to excite particles within the plasma cell. The stabilisation of the glow plasma can be used in glow discharge optical emission spectroscopy (GD-OES) for gas analysis and in other applications.