Stabilized Hypochlorite Cleaning Solutions via Chelation

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Solution Overview

Problem

Concentrated cleaning solutions tend to form visible precipitates upon storage or dilution, reducing their efficacy and aesthetic appeal, due to impurities in raw materials and diluents, and existing stabilization methods are costly and time-consuming.

Innovation Solution

Incorporating a small amount of chelating agents like EDTA, MGDA, or NTA into the cleaning solutions to prevent the formation of visible precipitates during storage and dilution, maintaining the solution's efficacy and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If commercially acceptable levels of impurities are present in raw materials, then cost is reduced and manufacturing is simplified, but visible precipitates form during storage and dilution

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidsolution stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

A chelating agent is introduced as an intermediary substance that binds to metal impurities in the raw materials, preventing them from reacting with the cleaning solution components to form precipitates. The chelating agent acts as a mediator between the impurities and the solution, allowing the use of cost-effective raw materials with acceptable impurity levels while maintaining solution stability during storage and dilution.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If two chemicals (phosphono compound and silicate) are added to stabilize the concentrated cleaning solution, then precipitate formation is prevented, but manufacturing cost and complexity increase

Engineering Contradiction:
Improvesolution stabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent combines the stabilizing function into a single chelating agent that performs the precipitate-prevention role previously requiring two separate chemicals (phosphono compound and silicate). This merging of functions reduces the number of ingredients needed, simplifies the manufacturing process, and lowers costs while achieving the same stability outcome.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The chelating agent serves multiple functions: it binds metal impurities, prevents precipitate formation, and maintains solution stability during both concentrated storage and dilution. This multi-functional approach replaces the need for multiple specialized additives, reducing manufacturing complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Duration of action of stationary object

If concentrated cleaning solution is stored for extended periods, then inventory availability is improved, but visible precipitates form reducing efficacy and aesthetic appeal

Engineering Contradiction:
Improvestorage durationVSAvoidsolution stability
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

The chelating agent is incorporated into the concentrated cleaning solution during manufacturing, performing preliminary stabilization before storage. This preliminary action binds potential precipitating agents in advance, allowing the solution to be stored for extended periods without forming visible precipitates, thereby maintaining both efficacy and aesthetic appeal throughout the storage duration.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of low concentrations of chelating agents effectively prevents the formation of visible precipitates for up to a year, enhancing the shelf stability and cost-efficiency of the cleaning solutions without compromising their bactericidal effectiveness.

Implementation Method 1

Incorporating a small amount of chelating agents like EDTA, MGDA, or NTA into the cleaning solutions to prevent the formation of visible precipitates during storage and dilution

Methodology Applied
Scientific EffectChelation:

Data Source

PatentEP2164944B1Stabilized concentrated cleaning solutions and methods of preparing the same
Publication Date: 2013.03.06 ECOLAB INC

AI summary

The invention is directed to stabilized concentrated cleaning solutions comprising a source of hypochlorite ions and to a method for providing the stabilized concentrated cleaning solutions. The stabilized concentrated cleaning solutions according to the invention comprise a hydroxide ion source, hypochlorite ion source, and a chelating agent, and are provided simply by mixing the various components together. The stabilized concentrated cleaning solutions exhibit stability against, e.g., dilution with a diluent comprising amounts of copper, iron, nickel cobalt, etc., as well as storage for periods of from about 10 weeks to up to about 1 year without undergoing visible deterioration and/or a substantial deterioration in efficacy.