Stabilized Photocurable Thiourethane Composition for Shorter Curing

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Solution Overview

Problem

Existing methods for producing thiourethane resin face challenges in controlling the quality of the composition and require a long curing time, making handling difficult.

Innovation Solution

A composition comprising a polyiso(thio)cyanate compound, a polythiol compound, and a stabilizer, which can be polymerized using light instead of heat, allowing for improved handleability and reduced curing time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of time

If heating method is used for curing composition, then thiourethane resin can be produced, but curing time becomes excessively long

Engineering Contradiction:
Improvecuring timeVSAvoidproduction efficiency
Core Design Contradiction:
Loss of timeVSProductivity

Solution Approach 1:

The patent replaces the thermal curing mechanism (heating) with a photochemical curing mechanism (light irradiation). By incorporating photopolymerization catalysts and using UV or visible light to initiate polymerization, the curing process transitions from thermal to optical energy activation, dramatically reducing curing time from hours to minutes or seconds while maintaining effective crosslinking of the thiourethane resin network.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental curing parameter from temperature (thermal energy) to light wavelength and intensity (photonic energy). By selecting appropriate photopolymerization catalysts that absorb specific wavelengths and adjusting light irradiation parameters, the curing process achieves rapid polymerization without excessive heat generation, solving the time-loss problem while controlling the curing kinetics through optical parameter optimization.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If composition is stored for quality control, then polymerization may occur during storage, but handling becomes difficult

Engineering Contradiction:
Improvequality controlVSAvoidhandleability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent divides the composition into separate components: polymerizable compounds (isocyanate and thiol groups) are stored separately from photopolymerization catalysts and initiators. This segmentation prevents premature polymerization during storage and transport, allowing each component to be handled independently without quality degradation. The components are combined only at the point of use and activated by light irradiation, ensuring both quality control and ease of handling throughout the supply chain.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary stabilization by incorporating stabilizers and inhibitors into the composition formulation that prevent spontaneous polymerization during storage. These preliminary protective measures allow the composition to be stored for extended periods without degradation, and the polymerization is activated only when needed through light irradiation, maintaining both quality integrity and operational convenience.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If heating is applied for curing, then polymerization proceeds, but energy consumption increases

Engineering Contradiction:
Improvecuring speedVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent substitutes thermal energy input (heating) with photonic energy input (light irradiation). By using UV or visible light sources to activate photopolymerization catalysts, the curing process consumes significantly less energy compared to conventional heating methods. The light energy directly triggers chemical bond formation without requiring bulk heating of the entire composition, reducing overall energy consumption while maintaining high curing speed and productivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes the phase transition from unreacted monomers/oligomers to crosslinked polymer network through photochemical activation. This phase transition is initiated by light absorption by photopolymerization catalysts, which triggers rapid polymerization without requiring thermal energy input. The transition occurs at ambient or controlled temperatures, eliminating the energy-intensive heating step while achieving complete curing and high productivity.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables the formation of thiourethane resin with enhanced handleability and faster curing, suitable for optical members requiring a high refractive index.

Implementation Method 1

a base generator (a); a polymerizable compound comprising at least one selected from the group consisting of a polyiso(thio)cyanate compound (b1) and a polythiol compound (c1)

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 2

a stabilizer (S)

Methodology Applied
Scientific EffectStabilization:

Data Source

PatentEP4644450A1Composition, composition kit, cured product, laminate, and method for producing cured product
Publication Date: 2025.11.05 MITSUI CHEMICALS INC
  • EP4644450A1 patent drawing
  • EP4644450A1 patent drawing
  • EP4644450A1 patent drawing

AI summary

A composition, including: a base generator (a); a polymerizable compound including at least one selected from the group consisting of a polyiso(thio)cyanate compound (b1) and a polythiol compound (c1); and a stabilizer (S).