Stabilizer Compound for Liquid Crystal UV Resistance

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Solution Overview

Problem

Liquid crystal compositions used in display elements, such as those for televisions, require high voltage holding ratio (VHR) to prevent deterioration from external stimuli like moisture, air, heat, and light, which is challenging to maintain without impairing storage stability and display quality.

Innovation Solution

A compound represented by General Formula (I) is introduced, which has high compatibility with liquid crystal compositions and enhances UV resistance, maintaining storage stability and preventing display defects like burn-in and unevenness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If antioxidants, ultraviolet absorbers, or light stabilizers are added to the liquid crystal composition to maintain high voltage holding ratio, then resistance to external stimuli is improved, but storage stability may be impaired

Engineering Contradiction:
Improveresistance to external stimuliVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention changes the chemical structure parameters of the stabilizer compound by introducing specific structural features (aromatic rings, electron-donating groups, electron-withdrawing groups) to optimize both UV absorption capability and storage stability. This structural parameter optimization allows the compound to resist external stimuli while maintaining compatibility with the liquid crystal composition.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite molecular structure combining multiple functional groups (aromatic rings, heteroatoms, substituent groups) within a single stabilizer compound. This composite structure enables the compound to simultaneously provide UV absorption, antioxidant properties, and storage stability without requiring multiple separate additives.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If stabilizer compounds are added to prevent deterioration, then UV resistance is improved, but compatibility with liquid crystal composition may be compromised

Engineering Contradiction:
ImproveUV resistanceVSAvoidcompatibility with liquid crystal composition
Core Design Contradiction:
Object-affected harmful factorsVSAdaptability or versatility

Solution Approach 1:

The invention optimizes physical-chemical parameters of the stabilizer compound including molecular weight, polarity, and structural flexibility to ensure compatibility with liquid crystal molecules. The compound's structural parameters are tuned to match the liquid crystal composition's characteristics, preventing phase separation or crystallization while maintaining UV resistance.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10329252B2Stabilizer compound, liquid crystal composition, and display element
Publication Date: 2019.06.25 DIC CORP
  • US10329252B2 patent drawing
  • US10329252B2 patent drawing
  • US10329252B2 patent drawing

AI summary

The present invention provides a compound represented by General Formula (I). The compound according to the present invention prevents the liquid crystal composition from being deteriorated due to light, has high compatibility with the liquid crystal composition, and does not impair the storage stability of the liquid crystal composition, thus the compound is useful as a constituent member of a liquid crystal composition. Since the liquid crystal composition and the liquid crystal display element containing the compound of the present invention exhibit UV resistance and have a high VHR, it is possible to obtain a liquid crystal display element with excellent display quality in which display defects such as burn-in and display unevenness do not occur or are suppressed.