Stable Fungicidal Compositions with Anionic Surfactants

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Solution Overview

Problem

Conazole fungicide compositions become unstable during storage and upon dilution with water, leading to thickening issues that render them unsuitable for use.

Innovation Solution

Incorporating an anionic surfactant into the fungicidal composition, which stabilizes the formulation and prevents significant viscosity increase during storage, maintaining pourability and chemical stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If conventional fungicide formulations are used, then initial effectiveness is maintained, but stability during storage deteriorates leading to thickening and phase separation

Engineering Contradiction:
Improvestability during storageVSAvoidusability after storage
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the formulation by introducing anionic surfactants (such as alkyl ether sulfates and alkyl phenol polyglycol ether sulfates) at specific concentrations (0.1-10% w/v). This parameter change fundamentally alters the stability characteristics of the conazole fungicide formulation, preventing thickening and phase separation during storage while maintaining pourability and chemical stability.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If the formulation is diluted with water for application, then coverage is improved, but stability deteriorates causing precipitation and loss of effectiveness

Engineering Contradiction:
ImprovedilutabilityVSAvoidstability upon dilution
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The anionic surfactant acts as an intermediary substance that mediates between the conazole fungicide and water during dilution. The surfactant molecules form micellar structures that solubilize the hydrophobic conazole compound, allowing it to remain stable and uniformly distributed in aqueous solutions at various dilutions without precipitation or phase separation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If inactive ingredients are added to improve formulation properties, then processability is enhanced, but chemical stability deteriorates due to incompatible interactions

Engineering Contradiction:
Improveformulation processabilityVSAvoidchemical stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by selecting specific anionic surfactants with particular molecular structures (such as sulfate ester groups and polyethylene oxide chains) that provide localized compatibility with conazole compounds. These surfactants create stable microenvironments around the fungicide molecules, allowing other formulation ingredients to be added without causing chemical degradation or instability.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The anionic surfactant enhances the stability of conazole fungicide compositions, ensuring they remain effective and usable over extended storage periods without phase separation or sedimentation, even at varying temperatures.

Implementation Method 1

Incorporating an anionic surfactant into the fungicidal composition, which stabilizes the formulation and prevents significant viscosity increase during storage

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

the anionic surfactant enhances the stability of conazole fungicide compositions, ensuring they remain effective and usable over extended storage periods without phase separation or sedimentation

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Data Source

PatentUS20240122181A1Stable fungicidal compositions
Publication Date: 2024.04.18 UPL CORPORATION LTD(MU)

AI summary

A stable agrochemical composition comprising at least one conazole fungicide, especially triticonazole and prothio-conazole; and at least one anionic surfactant is disclosed. Also disclosed is a process of preparing the agrochemical composition and a method of controlling fungi in a plant with the agrochemical composition.