Stable Silica Capsule Formulation for Fragrance Delivery

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Solution Overview

Problem

Existing fragrance delivery technologies, such as encapsulation in polymeric shells, often fail to significantly enhance the performance of fragrance materials in consumer products, leading to ongoing needs for improved delivery methods that provide sustained and effective release in personal care and fabric care products.

Innovation Solution

A flowable, stable silica capsule formulation is developed, incorporating core-shell silica capsules encapsulating fragrance materials and a polymeric adjuvant like polydiallyldimethylammonium chloride or vinyl pyrrolidone/dimethylaminoethyl methacrylate copolymer, which maintains stability for at least 4 weeks with minimal separation, enhancing the delivery and sensory performance of fragrances in various consumer products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polymeric encapsulation is used to protect fragrance material, then fragrance degradation and loss are prevented, but fragrance performance enhancement is insufficient

Engineering Contradiction:
Improvefragrance stabilityVSAvoidfragrance performance
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention uses a composite capsule structure with an inner polymeric shell for protection and an outer silica shell for enhanced performance. This dual-layer composite material approach combines the protective benefits of polymeric encapsulation with the performance-enhancing properties of silica, resolving the contradiction between stability and performance enhancement.

Inventive Principle:
Principle #40Composite materials

2Reliability

If silica encapsulation is used to prevent active ingredient release, then ingredient containment is improved, but delivery and release mechanisms are insufficient

Engineering Contradiction:
Improveingredient containmentVSAvoidactive ingredient delivery
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention applies local quality by creating different functional zones within the capsule structure. The inner polymeric layer provides containment and protection, while the outer silica layer provides enhanced delivery and controlled release properties. Each layer has localized qualities optimized for its specific function, resolving the contradiction between containment and delivery.

Inventive Principle:
Principle #3Local quality

3Productivity

If encapsulated fragrance is deposited in consumer products, then fragrance delivery is improved, but formulation stability and flowability are compromised

Engineering Contradiction:
Improvefragrance deliveryVSAvoidformulation stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The invention employs parameter changes by carefully controlling the particle size, surface properties, and composition ratios of the dual-layer capsules. These parameter optimizations ensure that the capsules maintain both their fragrance delivery capability and their stability within the consumer product formulation, preventing aggregation and maintaining flowability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The stable silica capsule formulation ensures prolonged fragrance stability and improved deposition, maintaining fragrance intensity and performance in personal care, fabric care, and home care products, offering enhanced consumer experience and product efficacy.

Implementation Method 1

the adjuvant is a polydiallyldimethylammonium chloride, vinyl pyrrolidone/dimethylaminoethyl methacrylate copolymer, or a combination thereof

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

polydiallyldimethylammonium chloride

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Data Source

PatentEP2862597B1Stable, flowable silica capsule formulation
Publication Date: 2018.01.03 INTERNATIONAL FLAVORS & FRAGRANCES INC
  • EP2862597B1 patent drawingFigure 1~2
  • EP2862597B1 patent drawing
  • EP2862597B1 patent drawing

AI summary

A flowable, stable silica capsule formulation composed of a silica capsule suspension and an adjuvant for use in a personal care product, a beauty care product, a fabric care product, a home care product, a personal hygiene product, an oral care product is provided.