Uneven Hygroscopic Film for Uniform Drying of Stacked Electrodes

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Solution Overview

Problem

The existing electrode drying methods for secondary batteries face challenges in uniformly drying electrodes, particularly those in the middle of a stacked configuration or at the core of a wound electrode sheet, leading to moisture content differences and reduced battery performance, requiring extended drying times or high temperatures that can damage the electrodes.

Innovation Solution

The method involves interposing a hygroscopic film with an uneven structure between electrodes or an electrode sheet, creating air flow paths that facilitate even drying, using materials like polyvinyl alcohol resin with adsorptive coatings to enhance moisture absorption and reduce drying time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If electrodes are stacked and dried together to improve manufacturing efficiency, then productivity increases, but moisture content uniformity deteriorates

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidmoisture content uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

A hygroscopic film is introduced as an intermediary substance between stacked electrodes. This film actively absorbs moisture from the electrode surfaces through capillary action and hygroscopic properties, mediating the drying process to achieve uniform moisture removal across all electrodes in the stack without requiring extended drying times

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The hygroscopic film utilizes porous structures with controlled pore sizes and distributions to enhance moisture absorption capacity. The porous architecture provides extensive surface area and capillary channels that facilitate rapid and uniform moisture extraction from electrode surfaces while maintaining structural integrity during the drying process

Inventive Principle:
Principle #31Porous materials

2Manufacturing precision

If drying time is extended to dry middle electrodes sufficiently, then moisture content uniformity improves, but productivity decreases

Engineering Contradiction:
Improvemoisture content uniformityVSAvoiddrying time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The hygroscopic film is pre-positioned between electrodes before the drying process begins. This preliminary arrangement ensures that moisture absorption capacity is already distributed throughout the electrode stack, enabling rapid and uniform drying from the outset without requiring extended drying times to achieve moisture uniformity in middle electrodes

Inventive Principle:
Principle #10Preliminary action

3Productivity

If drying temperature is increased to reduce drying time, then productivity improves, but electrode quality deteriorates

Engineering Contradiction:
Improvedrying timeVSAvoidelectrode quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The drying mechanism is substituted from thermal-driven evaporation to moisture-absorption-driven removal. Instead of relying on high temperature to evaporate moisture, the hygroscopic film passively absorbs moisture through capillary action and hygroscopic properties, enabling low-temperature drying that preserves electrode quality while achieving short drying times

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for nearly uniform drying of electrodes across the stack or wound sheet, significantly reducing drying time and moisture content differences, thereby improving battery performance and manufacturing efficiency.

Implementation Method 1

a hygroscopic film having an uneven structure is interposed between the electrodes

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

using materials like polyvinyl alcohol resin with adsorptive coatings to enhance moisture absorption

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

creating air flow paths that facilitate even drying

Methodology Applied
Scientific EffectConvection: Convection

Data Source

PatentEP3493301B1Electrode drying method
Publication Date: 2024.01.10 LG ENERGY SOLUTION LTD
  • EP3493301B1 patent drawingFigure 1~2
  • EP3493301B1 patent drawingFigure 3~4
  • EP3493301B1 patent drawingFigure 5~6

AI summary

Disclosed herein is an electrode drying method for drying a plurality of electrodes in the state in which the electrodes are stacked, the electrode drying method including interposing a hygroscopic film between the electrodes and drying the electrodes in the state in which the hygroscopic film is interposed between the electrodes, wherein at least one of the surfaces of the hygroscopic film that face the electrodes has an uneven structure, or an electrode drying method for drying an electrode sheet in the state in which the electrode sheet is wound, the electrode drying method including winding the electrode sheet with a hygroscopic film and drying the electrode sheet in the state in which the hygroscopic film is interposed between overlapping portions of the electrode sheet, wherein at least one of the surfaces of the hygroscopic film that are opposite the electrode sheet has an uneven structure.