Constrained Electrode Assembly for Battery Growth and Alignment
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Solution Overview
Problem
Existing secondary batteries face challenges with electrode expansion and contraction during cycling, leading to reliability and cycle life issues, as well as misalignment and mechanical instability, which can cause shorting and failure.
Innovation Solution
The use of a secondary battery design that incorporates a set of electrode constraints, including a primary and secondary growth constraint system, to control the expansion and contraction of electrodes and maintain alignment, thereby enhancing mechanical stability and reducing the risk of shorting.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Adaptability or versatility
If electrodes are allowed to expand and contract freely during battery cycling, then the battery can accommodate volume changes of active materials, but electrical shorts and battery failures occur due to electrode expansion
Solution Approach 1:
The battery is divided into separate functional zones: a first battery portion containing the anode and its expansion space, and a second battery portion containing the cathode. This segmentation allows independent management of expansion for each electrode type, accommodating volume changes while preventing interference between electrodes that would cause shorts.
Solution Approach 2:
The patent introduces a longitudinal dimension for battery expansion by allowing the anode to expand into a first expansion space along the longitudinal axis, rather than only in planar dimensions. This dimensional approach accommodates volume changes while maintaining separation from the cathode, preventing electrical shorts.
2Ease of manufacture
If electrode alignment is not controlled, then manufacturing is simpler, but mismatch in electrode alignment caused by physical or mechanical stresses leads to shorting and failure
Solution Approach 1:
The battery structure is pre-configured with designated expansion spaces and constrained geometries before cycling begins. The anode is positioned within a defined first battery portion with predetermined expansion boundaries, ensuring that even under mechanical stress, the anode cannot shift into positions that would cause misalignment or shorting with the cathode.
3Reliability
If the battery footprint is increased to provide expansion space, then electrode expansion is accommodated, but the battery size increases excessively
Solution Approach 1:
The patent employs a flexible separator that can deform to accommodate anode expansion while maintaining electrical isolation. This flexible boundary allows the anode to expand into the designated space without requiring rigid, space-consuming containment structures, thus accommodating expansion while minimizing footprint increase.
4Reliability
If mechanical constraints are added to control electrode expansion, then reliability improves, but device complexity increases
Solution Approach 1:
The functional elements are merged into integrated components: the separator serves both as an electrical insulator and as a flexible constraint that guides anode expansion; the battery portion divisions serve both as structural organizers and as expansion boundaries. This merging reduces the need for separate, complex constraint mechanisms while maintaining electrode stability and reliability.
Data Source
AI summary
Embodiments of secondary batteries having electrode assemblies are provided. A secondary battery can comprise an electrode assembly having a stacked series of layers, the stacked series of layers having an offset between electrode and counter-electrode layers in a unit cell member of the stacked series. A set of constraints can be provided with a primary constraint system with first and second primary growth constraints separated from each other in a longitudinal direction, and connected by at least one primary connecting member, and a secondary constraint system comprises first and second secondary growth constraints separated in a second direction and connected by members of the stacked series of layers. The primary constraint system may at least partially restrain growth of the electrode assembly in the longitudinal direction, and the secondary constraint system may at least partially restrain growth in the second direction that is orthogonal to the longitudinal direction.


