Semiconductor device, memory device, and method for forming transistor on substrate

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Solution Overview

Problem

The performance of CMOS transistors in semiconductor memory devices deteriorates during manufacturing, leading to issues such as increased resistance at interfaces, etching residue formation, and reduced yield due to phosphorus diffusion and abnormal oxidation, which affects the reliability and integration of three-dimensional stacked non-volatile memory devices.

Innovation Solution

A semiconductor device with a three-layer stacked semiconductor structure, comprising a phosphorus-doped polycrystalline semiconductor first layer, a carbon-doped polycrystalline semiconductor second layer, and a phosphorus-doped or undoped polycrystalline semiconductor third layer, where the third layer has a lower phosphorus content to prevent etching residue and oxidation, and a TSI layer is used to prevent impurity diffusion, improving the interface resistance and manufacturing yield.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If phosphorus doping is used to improve electrical conductivity in the semiconductor layer, then electrical performance is improved, but phosphorus diffusion and segregation occur causing etching residue and performance deterioration

Engineering Contradiction:
Improveelectrical performanceVSAvoidetching residue formation
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

A carbon-doped polycrystalline semiconductor layer is introduced as an intermediary barrier layer between phosphorus-doped regions. This carbon-doped layer prevents phosphorus diffusion and segregation during manufacturing processes, thereby eliminating etching residue while maintaining the electrical performance benefits of phosphorus doping in the adjacent layers.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The semiconductor structure is divided into multiple functional layers with distinct doping profiles. Instead of uniform phosphorus doping, the invention segments the structure into phosphorus-doped regions for electrical conductivity and carbon-doped regions as diffusion barriers, allowing each layer to perform its specific function without interfering with the other.

Inventive Principle:
Principle #1Segmentation

2Productivity

If three-dimensional stacked structure is implemented to increase integration, then device density is improved, but interface resistance increases affecting transistor performance

Engineering Contradiction:
Improvedevice integration densityVSAvoidinterface resistance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention applies different doping characteristics to different layers within the stacked structure. Each interface region is optimized with appropriate doping concentrations and types (phosphorus for conductivity, carbon for barrier properties), ensuring that local interface quality maintains low resistance while the overall three-dimensional structure achieves high integration density.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances transistor performance by preventing etching residue and phosphorus segregation, reducing defects and increasing the yield of CMOS transistors, thereby improving the reliability and integration of three-dimensional stacked non-volatile memory devices.

Implementation Method 1

a carbon-doped polycrystalline semiconductor second layer... to prevent etching residue and phosphorus segregation

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

a first layer formed on the gate insulating layer and including a phosphorus-doped polycrystalline semiconductor... a third layer formed on the second layer and including a phosphorus-doped or undoped polycrystalline semiconductor

Methodology Applied
Scientific EffectDoping: Dopants

Implementation Method 3

a TSI layer is used to prevent impurity diffusion

Methodology Applied
Scientific EffectPhysical barrier: Physical Containment

Data Source

PatentUS11910610B2Semiconductor device, memory device, and method for forming transistor on substrate
Publication Date: 2024.02.20 KIOXIA CORP
  • US11910610B2 patent drawing
  • US11910610B2 patent drawing
  • US11910610B2 patent drawing

AI summary

A semiconductor device includes a substrate, a gate insulating layer on the substrate, and a stacked semiconductor layer. The stacked semiconductor layer includes a first layer formed on the gate insulating layer and including a phosphorus-doped polycrystalline semiconductor, a second layer formed on the first layer and including a carbon-doped polycrystalline semiconductor, and a third layer formed on the second layer and including a phosphorus-doped or undoped polycrystalline semiconductor. The semiconductor device further includes a metal layer on or above the stacked semiconductor layer. The third layer includes less phosphorus than the first layer or does not include phosphorus.