Hydrogen Chloride Gas Dehydration With Staged Sulfuric Acid

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Solution Overview

Problem

Existing methods for hydrogen chloride gas dehydration using concentrated sulfuric acid are inefficient, leading to a trade-off between water concentration and sulfuric acid concentration, necessitating high concentrations of sulfuric acid for effective dehydration.

Innovation Solution

A multi-step dehydration process involving multiple drying columns with varying sulfuric acid concentrations, where the second and subsequent steps use higher concentrations of sulfuric acid than the first, optimizing the use of sulfuric acid throughout the process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a large amount of high-concentration concentrated sulfuric acid is used to increase the certainty of dehydration, then the dehydration reliability is improved, but the cost and sulfuric acid utilization efficiency deteriorate

Engineering Contradiction:
Improvedehydration certaintyVSAvoidsulfuric acid utilization efficiency
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The dehydration process is divided into multiple stages with different sulfuric acid concentrations. The first drying column uses concentrated sulfuric acid (93-98 wt%) for initial dehydration, while the second drying column uses higher concentration sulfuric acid (96-98 wt%) for final dehydration. This segmentation allows each stage to perform its specific function optimally, improving overall dehydration reliability while reducing total sulfuric acid consumption compared to using only high-concentration acid throughout.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the concentration parameter of sulfuric acid across different stages of the dehydration process. By using 93-98 wt% sulfuric acid in the first stage and 96-98 wt% in the second stage, the system optimizes the balance between dehydration effectiveness and acid utilization efficiency. This parameter variation resolves the contradiction by matching acid concentration to the specific dehydration needs at each stage.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the concentration of concentrated sulfuric acid is decreased to treat high water concentration hydrogen chloride gas, then the treatment capacity is improved, but the dehydration reliability deteriorates

Engineering Contradiction:
Improvetreatment capacityVSAvoiddehydration certainty
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The system segments the dehydration task into two columns handling different dehydration loads. The first column with 93-98 wt% sulfuric acid handles the bulk water removal from high-concentration HCl gas, providing high treatment capacity. The second column with 96-98 wt% sulfuric acid provides the final dehydration guarantee, ensuring reliability. This segmentation resolves the contradiction between treatment capacity and dehydration certainty.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies different sulfuric acid concentration parameters to different stages: 93-98 wt% for the first stage (high capacity) and 96-98 wt% for the second stage (high reliability). This parameter change strategy allows the system to achieve both high treatment capacity and high dehydration certainty simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enhances the efficiency of sulfuric acid utilization, achieving effective dehydration with reduced sulfuric acid usage and improved dehydration certainty.

Implementation Method 1

a first dehydration step of bringing hydrogen chloride gas and concentrated sulfuric acid into contact with each other; and a second dehydration step of bringing hydrogen chloride gas that has been obtained through the first dehydration step into contact with concentrated sulfuric acid

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS12404172B2Hydrogen chloride dehydration method
Publication Date: 2025.09.02 TOKUYAMA CORP
  • US12404172B2 patent drawing
  • US12404172B2 patent drawing
  • US12404172B2 patent drawing

AI summary

A dehydration method in accordance with an embodiment of the present invention includes: a first dehydration step of bringing hydrogen chloride gas (21) and concentrated sulfuric acid (13A) into contact with each other; and a second dehydration step of bringing hydrogen chloride gas (21A) that has been obtained through the first dehydration step into contact with concentrated sulfuric acid (13B). A concentration of the concentrated sulfuric acid used in the second dehydration step is higher than a concentration of the concentrated sulfuric acid used in the first dehydration step.