Staggered Adsorption Bed for Seawater Desalination Waste Heat Recovery

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Solution Overview

Problem

Current seawater desalination processes face energy waste due to inefficient heat management, particularly in the form of wasted heat from steam condensation, and existing heat storage technologies suffer from low energy density and stability issues, limiting the effective utilization of intermittent energy sources like solar and geothermal energy.

Innovation Solution

A staggered and crossed heat storage adsorption bed system that incorporates a vacuum heat insulation layer with a double-layer stainless steel structure and a unique arrangement of adsorption boxes to enhance heat storage density and efficiency, allowing for the efficient capture and storage of waste heat from seawater desalination processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional heat storage methods (sensible or latent heat storage) are used, then the system is simple and reliable, but the heat storage density is low and heat loss is large

Engineering Contradiction:
Improveheat lossVSAvoiddevice complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent changes the fundamental parameter of heat storage mechanism from physical (sensible/latent heat) to chemical (thermochemical adsorption). This transformation enables high heat storage density (0.5-3 GJ/m³) and negligible heat loss during storage, as the energy is stored in chemical bonds rather than thermal energy, eliminating the need for continuous thermal insulation systems.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite adsorption materials combining metal oxides (such as CuO, ZnO, NiO) with support structures. These composite materials achieve high reaction conversion rates and fast kinetics while maintaining structural stability, resolving the contradiction between high performance and material complexity.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If thermochemical energy storage is used, then the heat storage density is high and heat loss is negligible, but the storage medium undergoes degradation and the device structure becomes complex

Engineering Contradiction:
Improveheat storage densityVSAvoidstorage medium stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent applies local quality optimization by selectively coating adsorption materials in specific zones of the reactor and using different material compositions in different regions to optimize both reaction performance and structural stability. The support structure provides mechanical stability while the active coating layers provide high heat storage density.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent optimizes operational parameters such as temperature cycles, pressure conditions, and gas flow rates to prevent degradation of the storage medium. By controlling these parameters within optimal ranges, the system achieves high heat storage density while maintaining long-term stability of the thermochemical materials.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional heat storage is used, then the system is simple, but the reaction conversion rate and reaction rate are low

Engineering Contradiction:
Improvereaction rateVSAvoiddevice complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent segments the adsorption bed into multiple zones with different functional characteristics, allowing simultaneous optimization of heat storage, heat release, and material stability. This segmentation enables high reaction rates in active zones while maintaining overall system simplicity through modular design.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent utilizes porous adsorption materials with high surface area and controlled pore structures. These materials provide numerous active sites for rapid thermochemical reactions, achieving high reaction rates and conversion efficiency while maintaining manageable device complexity through standardized material selection.

Inventive Principle:
Principle #31Porous materials

4Loss of energy

If waste heat from steam condensation is not utilized, then the process is simple, but energy is wasted and heat supply-demand mismatch occurs

Engineering Contradiction:
Improvewaste heat lossVSAvoidheat management complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent converts the harmful waste heat from steam condensation into a useful resource by capturing it through the thermochemical adsorption system. The waste heat drives the endothermic adsorption reactions, storing energy that can be released later when heat is needed, thus eliminating energy waste and balancing supply-demand mismatches.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent designs a multi-functional system that simultaneously performs desalination, waste heat recovery, and heat storage. The same thermochemical materials and reactor structure serve multiple purposes: separating water from seawater, capturing waste heat from condensation, and storing thermal energy for later use, thereby reducing overall system complexity despite the multiple functions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves high heat storage density with minimal loss, fast reaction rates, and improved heat utilization, effectively addressing the inefficiencies in existing technologies by utilizing low-grade energy and enhancing the recyclability of adsorption materials.

Implementation Method 1

an adsorption cavity (11), wherein a vacuum heat insulation layer (13) arranged at an outermost side of the adsorption cavity (11)

Methodology Applied
Scientific EffectVacuum insulation: Vacuum

Implementation Method 2

vacuum heat insulation layer (13)

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 3

the adsorption cavity (11) includes a plurality of adsorption substrates (15) for filling adsorption substrates

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

dry-hot gas first enters a first layer adsorption formed by the corner end adsorption box (15) and the central adsorption box (16) from the inlet cavity (12), and then diffuses along an airflow direction to enter a second layer adsorption formed by the side adsorption box (17) according to an air diffusion principle

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS11964229B1Staggered and crossed heat storage adsorption bed and seawater desalination waste heat storage system
Publication Date: 2024.04.23 ENERGY RES INST OF SHANDONG ACAD OF SCI
  • US11964229B1 patent drawing
  • US11964229B1 patent drawing
  • US11964229B1 patent drawing

AI summary

A staggered and crossed heat storage adsorption bed and a seawater desalination waste heat storage system are provided, which relate to the field of seawater desalination and the technical field of thermochemical adsorption heat storage. The adsorption bed includes a bed body, wherein an adsorption cavity is arranged in the bed body; two sides of the adsorption cavity are respectively communicated with an inlet cavity and an outlet cavity; the adsorption cavity includes a vacuum heat insulation layer arranged at an outermost side; the vacuum heat insulation layer is embedded with an adsorption box fixing layer; a corner end adsorption box, a central adsorption box and a side adsorption box are staggered and crossed arranged in an inner cavity of the vacuum heat insulation layer through the adsorption box fixing layer.